Safety Data Sheet
Protectol® PE
Revision date : 2012/02/07 Page: 1/8 Version: 1.0 (30063180/SDS_GEN_US/EN) 1. Product and Company Identification
24 Hour Emergency Respon Information
Company
BASF CORPORATION
100 Campus Drive
Florham Park, NJ 07932, USA CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP
2. Hazards Identification
Emergency overview
WARNING:
Caus eye irritation.
MAY CAUSE SKIN IRRITATION.
can you feelingMAY CAUSE RESPIRATORY TRACT IRRITATION.
INGESTION MAY CAUSE GASTRIC DISTURBANCES.
Avoid contact with the skin, eyes and clothing.
Avoid inhalation of dusts/mists/vapours.
U with local exhaust ventilation.
Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator.
Wear NIOSH-certified chemical goggles.
latecome
Wear protective clothing.
Wear chemical resistant protective gloves.
Eye wash fountains must be easily accessible.
State of matter: liquid
Colour: colourless
Odour: faint specific odour
Potential health effects
Primary routes of exposure:
Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gas include inhalation and eye contact. Skin contact may be a route of entry for liquified gas.
Irritation / corrosion:
Not irritating to the skin. Eye contact caus irritation.
Sensitization:
Skin nsitizing effects were not obrved in animal studies.
Chronic toxicity:
Carcinogenicity: No data available concerning carcinogenic effects.
Version: 1.0 (30063180/SDS_GEN_US/EN) Reproductive toxicity: The results of animal studies gave no indication of a fertility impairing effect.
Teratogenicity: Animal studies gave no indication of a developmental toxic effect at dos that were not toxic to the parental animals.
Genotoxicity: The substance was not mutagenic in bacteria. No mutagenic effect was found in various tests with mammalian cell culture and mammals.
Signs and symptoms of overexposure:
Overexposure may cau:, vomiting, lethargy, giddiness, naua, coughing, headache
Potential environmental effects
Aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations.
3. Composition / Information on Ingredients
CAS Number Content (W/W)Chemical name
122-99-6 >= 99.0 - <= 100.0 %2-Phenoxyethanol
4. First-Aid Measures
General advice:
Remove contaminated clothing.
If inhaled:
Remove the affected individual into fresh air and keep the person calm. Seek medical attention.
If on skin:
Wash thoroughly with soap and water.
If irritation develops, ek medical attention.
If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye
specialist.
If swallowed:
Immediately rin mouth and then drink plenty of water, do not induce vomiting, ek medical attention. Never induce vomiting or give anything by mouth if the victim is unconscious or having con
vulsions.
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no known
specific antidote.
5. Fire-Fighting Measures
Flash point: 126 °C (Directive 92/69/EEC, A.9, clod cup)
Autoignition: 475 °C (DIN 51794)
Lower explosion limit: 1.4 %(V)
Upper explosion limit: 9.0 %(V)
ignite
Flammability: does
not
Version: 1.0 (30063180/SDS_GEN_US/EN) Self-ignition temperature: Bad on its structural properties the
product is not classified as lf-igniting.
Suitable extinguishing media:
water spray, dry powder, foam
Hazards during fire-fighting:
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be relead in ca of fire.
Vapours may form explosive mixture with air.
Protective equipment for fire-fighting:
Firefighters should be equipped with lf-contained breathing apparatus and turn-out gear.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be dispod of in accordance with official regulations.
Impact Sensitivity:
Remarks: Bad on the chemical structure there is no shock-nsitivity.
6. Accidental relea measures
Personal precautions:
英孚教育价格U personal protective clothing. Information regarding personal protective measures e, chapter 8.个人理财试题
Environmental precautions:
Do not discharge into drains/surface waters/groundwater.keep on
Cleanup:
Place absorbed material in the same container as the spilled substance/product for disposal.
For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpo binder). Dispo of absorbed material in accordance with regulations.
courtesyFor large amounts: Pump off product.
nuts是什么意思英语Further information:
High risk of slipping due to leakage/spillage of product.
7. Handling and Storage
Handling
General advice:
Prevent contact with air/oxygen (formation of peroxide).
No special measures necessary provided product is ud correctly.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Storage
General advice:
Keep container tightly clod in a cool, well-ventilated place. Keep under nitrogen. Protect from atmospheric humidity.
Storage incompatibility:
General advice: Segregate from foodstuffs.
Storage stability:
Version: 1.0 (30063180/SDS_GEN_US/EN) May form explosive peroxides.
8. Exposure Controls and Personal Protection
Advice on system design:
All ventilation methods taken should correspond to the processing conditions.
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Breathing protection if breathable aerosols/dust are formed.
Hand protection:
Chemical resistant protective gloves
Eye protection:
Tightly fitting safety goggles (chemical goggles) and face shield.
Body protection:
light protective clothing
General safety and hygiene measures:
Wear protective clothing as necessary to minimize contact. Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Avoid contact with skin and eyes.
Remove contaminated clothing.
9. Physical and Chemical Properties
Form: liquid
odour
specific
Odour: faintboulevard of broken dreams
Colour: colourless
pH value: 7 ( 20 °C)
Melting point: 9.1 °C ( 1,013 hPa) (Directive 92/69/EEC, A.1)
Boiling point: 244.3 °C (Directive 92/69/EEC, A.2)
decomposition point: > 350 °C (OECD Guideline 103)
Vapour pressure: 0.01 hPa ( 20 °C)
Density: 1.11 g/cm3 ( 20 °C)
Relative density: 1.11 ( 20 °C) (Directive 92/69/EEC, A.3)
Vapour density: Heavier than air.
1.2 ( 23 °C) (OECD Guideline 107)
Partitioning coefficient
n-octanol/water (log Pow):
Viscosity, dynamic: 41 mPa.s ( 19.8 °C) (OECD 114)
19 mPa.s ( 40.5 °C) (OECD 114)
Particle size:
The substance / product is marketed or
ud in a non solid or granular form.
Solubility in water: 24 g/l ( 20 °C)
10. Stability and Reactivity
Conditions to avoid:
Avoid contact with air. Avoid moisture. Avoid heat.
变化无常英语Substances to avoid:
strong oxidizing agents
Hazardous reactions:
The product is stable if stored and handled as prescribed/indicated.
Version: 1.0 (30063180/SDS_GEN_US/EN) May form explosive peroxides when expod to air. Substance/product can form explosive mixture with air.
Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Oxidizing properties:
Bad on its structural properties the product is not classified as oxidizing.
11. Toxicological information
Acute toxicity
Oral:
Type of value: LD50
Species: rat
Value: 2,740 mg/kg (BASF-Test)
The European Union (EU) has classified this substance as 'harmful'.
Inhalation:
Species: rat
Value: (IRT)
Exposure time: 8 h
No mortality within the stated exposition time as shown in animal studies.
Dermal:
Type of value: LD50
Species: rabbit
Value: 5,000 mg/kg
Irritation / corrosion
Skin:
Species: rabbit
Result: non-irritant
Method: OECD Guideline 404
Eye:
Species: rabbit
Result: Irritant.
Method: OECD Guideline 405
Sensitization:biceps
Guinea pig maximization test
Species: guinea pig
Result: Non-nsitizing.
Method: OECD Guideline 406
12. Ecological Information
Fish
Acute:
Flow through.
Pimephales promelas/LC50 (96 h): 344 mg/l
The statement of the toxic effect relates to the analytically determined concentration.
Chronic:
