专利名称:Selective aliphatic C-H oxidation
6级成绩查询时间发明人:M. Christina White,Mark S. Chen元吉
llosa
申请号:US12245086
申请日:20081003
公开号:US07829342B2
公开日:
20101109
专利内容由知识产权出版社提供
专利附图:钢铁侠3主题曲
摘要:A composition including a complex of a metal, a tetradentate ligand, at least one ancillary ligand, and a counterion may be ud for lective spC—H bond oxidation.The tetradentate ligand may include a N-heterocyclic-N,N′-bis(pyridyl)-ethane-1,2-
sdfs
diamine group or a N,N′-bis(heterocyclic)-N,N′-bis(pyridyl)-ethane-1,2-diamine group. The
jdf
composition can be ud in combination with HOto effect highly lective oxidations of unactivated spC—H bonds over a broad range of substrates. The site of oxidation can be predicted, bad on the electronic and/or steric environment of the C—H bond. In addition, the oxidation reaction does not require the prence of directing groups in the substrate.
申请人:M. Christina White,Mark S. Chenchill out
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地址:Champaign IL US,Champaign IL US
国籍:US,US
代理机构:Blanchard & Associates
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