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更新时间:2023-05-27 05:51:10 阅读: 评论:0

Development of an Low Cost Wafer Level Flip Chip Asmbly Process for High Brightness LEDs Using the AuSn Metallurgy
Gordon Elger, Rafael Jordan, Maria v. Suchodoletz and Hermann Oppermann
Fraunhofer Institute for Reliability and Microintegration
Berlin, Germany
Abstract
A low cost wafer level packaging process for bumped flip-chip LEDs (light emitting diodes) is demonstrated. The GaAlAs-LEDs are picked from blue tape and placed on the silicon 4"-substrate wafer containing more than 2000 single substrates. After reflow soldering in an infrared oven under active atmosphere, the wafer is diced and the components are individualized. The pick and place process, the tacking of the LEDs on the wafer and the reflow soldering process are investigated to obtain a high process yield.
Due to the flip chip design all electrical contacts are formed in one asmbly step and wire bonding isn't necessary. Another advantage is the good heat transfer to the substrate due to the p-side down co
nnection that allows high current and therefore high brightness of the LED.
Au80Sn20 solder is ud for the electrical and mechanical interconnection. The AuSn solder is applied in different ways: Sn is either electroplated on the Au-contacts of the LEDs or as a pad on the Au metallization of the substrates. The metallurgy of the solder process and the reliability of the LEDs are investigated. The amount of Au and Sn was adjusted, i.e. the thickness of the electroplated Au and Sn layers, to achieve interconnections formed by the intermetallic phas AuSn and ζ of the Au80Sn20 eutectic solder. Due to the good mechanical properties, the good thermal conductivity and the low growth of intermetallic phas the reliability of the contacts is very high. It is demonstrated that the performance of the LED is excellent and the degradation is very small. Due to the high melting point of Au80Sn20 solder (278°C) the component can be ud in SMD process without remelting of the LED contacts.
Introduction
Since LEDs were developed in the 1960th the
market has grown rapidly. Constantly, the
efficiency and the brightness of the LEDs have
been incread by the employment of new
technologies.
Flip-Chip LEDs (FC-LEDs) have the n- and p-
contact on one side. All electric contacts can be
sheldon语录
joined to the substrate in one asmbly step. The
asmbly process, investigated in this paper, was
developed for a high brightness FC-LED, which
has one p- and two n-contact  (e Fig. 1), manufactured by the company EPIGAP. The p- and the n-contact are in the same plane. This is achieved by an etching technique for GaAs (e Fig. 2). The flip-chip is ud to realize high power LEDs on a small area without any wire bond. The chip is soldered with the contacts on a SMD-type carrier. The light is emitted to the rear side of the chip intensified by the reflector. No bonding wire disturbs the light output. Becau the p-n-junction is near to the area of the electrical contact, which itlf can be soldered directly on a heat sink, the heat
transfer is excellent. High current and, therefore, high radiant output power can be achieved. Without wire bonds the reliability is improved compared to standard devices and handling is easier. Also arrays of flip-chip-LEDs can be realized with very narrow distances between the single devices due to the low thermal resistance of the asmbly.
Fig. 1 Flip-Chip LED on substrate
贝克汉姆4亿豪宅To increa the reliability of the component the metallurgy of the solder joints were modified. Instead of tin-rich solder joints Au-rich solder joints (Au80Sn20) were established. The substrate metallization was redesigned in a way that the project partner EPIGAP is still able to perform the plating in his own facilities.
Au80Sn20 (gold 80wt% and tin 20wt%) is a reliable solder applied for flip-chip asmblies. A detailed description of the technical application is given in [1,2]. An advantage for optoelectronic
components is that the Au80Sn20 solder can be ud in a flux-free process. The melting point of Au80Sn20 is 278°C and, therefore, higher than the temperature of SMD reflow process. The mounted LEDs can be ud as SMDs when soldered with Au80Sn20. Reliability investigations were performed to demonstrate the superiority of the achieved Au-rich interconnection compared to the earlier Sn-rich interconnection [3].
Usually, the AuSn solder is ud in its eutectic composition as solder preforms, AuSn-bumps or metallization layers on the substrate. Typically, 1.5 µm Au-layer per 1µm Sn-layer is necessary to achieve the Au/Sn ratio of the Au80Sn20 solder. In this paper, the solderability is investigated when the solder compounds, gold and tin, are electroplated parated on different sides.  The LED contacts and the substrate pads were Au-plated. Tin was either electroplated on the Au metallized substrate pads or on the Au contacts of the LEDs. The solderability of both layouts were investigated. When the tin is plated on the LED wafer the situation is similar to AuSn chip-wafer bumping described in [4,5,6].  However, usually after electroplating a parated reflow step is performed for forming the eutectic AuSn solder caps of the bump.
bao
Asmbly
Fig. 2 Flip-Chip design
For the asmbly two different strategies were investigated. On the one hand single chip thermode bonding on the other hand reflow bonding on wafer level.
Fig. 4 Asmbled LEDs on a silicon substrate For the thermode bonding a flip-chip bonder from Karl-Suss with an accuracy of ± 1µm was ud. The chip is picked by a vacuum tool (arm) from a waffle pack. The substrate is fixed on the bonding table (chuck) also by vacuum. The chip is aligned on the substrate using a simultaneous up and down looking microscope. After the alignment the chip is placed on the substrate and hold in this position for the whole bonding process with a given small force. Becau arm and chuck can be heated parately, the heating profile for soldering can be adjusted taking into account the different thermal mass of chip and substrate. Additionally the manner of melting can be influenced. Maximum heating rates are about 40K/s and a bonding cycle is about 75s. The advantage of thermode bonding is the high accuracy. But heating the tool and changing the
substrate for each die increas the bond cycle compared to a simple pick and place process. Using
the reflow-process the whole substrate wafer is populated with a maximum rate of 3s/die. The wafer (4") with about 2250 LEDs will than soldered in one step, so the longer soldering cycle of 3-5min is negligible.
Fig. 3 BSE picture of a cross ction of a LED asmbly after reflow (C, 290°C)
The common solution for the packaging of the LEDs is the following process: The LEDs are offered face up on blue tape; the LEDs are flipped by a flip-unit during the picking process of the machine. The dies were detached from the blue tape using a die eject system with a small needle. After flipping, the LEDs are placed on the substrate wafer. Important for the process yield is the tacking of the LEDs becau the populating of the wafer takes more than one hour. After reflowing the
whole wafer (Fig. 4), the components are
individualized by dicing the wafer.
环保材料 英语
Fig. 6 AuSn-pha diagramm [7]
honFor automatic asmbly an apm2200 from DATACON with an maximum accuracy of ± 10µm was ud. Running the common way of placing the LEDs have shown, that the vacuum tool can not grip the die on the bump side as reliable as on the flat surface. Additionally flipping the die needs more time. Therefore the LEDs are now placed face down on the blue tape to avoid the flipping step. Picki
ng the LEDs with the bond arm is less difficult becau it can be synchronized with the needle system. This prevent from damaging the nsitive LEDs. To increa the gripping force of the pick and place arm a special rectangle tool with the exact size of the LED was build.
Under this conditions a reliable pick and place process can be run (Fig. 5).
To increa the picking time from the blue tape it is
still under investigation to u a green tape. The green tape loos his adhesion by heating to about 90°C.
智慧工程AuSn metallurgy
The metallurgy of the AuSn system has been discusd earlier [1,4-6].  The pha diagram is shown in Fig. 6 [7]. The first Sn-rich eutectic Au10Sn90 forms at 217°C. The Sn-rich eutectic consists of Sn and AuSn 4. The Au10Sn90 eutectic is known to be brittle. With increasing Au content the Au-richer intermetallic phas AuSn 2 and AuSn can be obrved. The melting point of the Au-rich eutectic Au80Sn20 is 278°C. It is formed by the solid phas AuSn and ζ (Au 5Sn). Increasing the temperature more Au can be dissolved in the liquid pha. If excess Au is available at a given
temperature formation of ζ-pha is obrved. The growth of the ζ-pha is diffusion controlled and, therefore, depends on the thickness of the ζ-pha layer. Although the growth rate is quite small, a four micron thick ζ-pha layer forms at 290°C in 25s. The ζ-pha is stable up to 519°C; it has good mechanical properties, i.e. a lower Vickers microhardeness than eutectic Au80Sn20, an incread thermal conductivity and an excellent reliability [5,8]. Therefore, it is suited also for high power applic
ations [9]. Contacts formed by the ζ-pha don’t remelt at the Au80Sn20 reflow temperature any more and show a better performance [6]. Working with the ζ-pha offers the possibility to u the fluxfree AuSn metallurgy on different asmbly hierarchies of optoelectronic modules without remelting the interconnections
soldered at previous asmbly steps.
Fig. 5 Part of a soldered wafer
equivalentsMetallization
chip pad substrate
10 m Au  µ
7 m Au µ5 m Au µ
Au
3-5 m Au µ
10 m Au
µ
4 m Sn
µ
Sn
10-16 m Sn µ
6 m Au µ
A
B
C
D
tin on substrate
bumped  LED
Fig. 7 Metallization scheme. GaAlAs Chip: Au electroplated on an AuGe contact, silicon
substrate: Sn electroplated on 3 µm Cu/0.5 µm Ti. For the asmbly C, the Sn is patterned (undersize pad) and an Au layer is introduced between Cu-layer and Sn-pad. For metallization type D the LED wafer was bumped by plating 5µm tin on 7µm Au contacts.
For the previous tin-rich solder contacts the silicon substrate was metallized as follows: 10 µm Sn-
layer over 3 µm Cu and 0.5 µm Ti. The chip was electroplated with 3-6 µm Au over an AuGe contact (metallization type A, Fig. 7). The thickness of the metallization was changed to form interconnections with the Au-rich Au80Sn20 solder. In Fig. 7 the different metallization types are shown schematically. The thickness of the Sn-layer could not be reduced to less than 4 µm due to the electroplating process of EPIGAP. Therefore, the Au-layer on the contacts of the chip was incread
to 10 µm and the Sn-layer was decread to 4 µm (metallization type B, Fig. 7). In a cond step, a
gold layer was introduced on the Si substrate over the Cu-layer. This Au-layer has two functions: One
is to increa the amount of Au, the other is that an Au-layer on Cu can parate the AuSn solder from the Cu which effects long time reliability [10 Zakel (1994)]. The Sn was patterned on the Au-layer (metallization type C, Fig. 7). The pad size is crucial for the asmbly. As the pad formed by the tin was larger than the gold pad on the LED (ca A and B, Fig. 7), the excessive tin flew into the joining area. By using undersized pads the amount
of tin was reduced without having to reduce the thickness. Becau of the excellent wetting properties of AuSn solder, the interconnection area
is not decread by using undersized pads (e Fig. 10). Finally, the LED wafer was bumped by plating
5µm tin on 7µm Au contacts (metallization type D). The substrates ud for soldering this bumped LEDs had 3-5µ
m Au on a Ti adhesion layer. Fig. 8 BSE picture of a LED after reflow (A, 280°C) The bright domains are AuSn4 and the dark domains pure Sn. Notable is the crack (top). Large cracks were often found in the Au10Sn90 eutectic (AuSn4/Sn domains). With excess of Sn, the typical structure of the eutectic  Au10Sn90 is found (bottom). Becau the Sn-layer was larger than the Au-pad of the chip, large amounts of solder flew
into the joint area.
Au
AuSn
AuSn
η
2
Fig. 9 BSE picture of the solder interconnection of a LED (B,240°C). The pha η contains 50% Sn, 25% Au and 25%Cu (at%).
Reflow soldering of LEDs
The metallurgic phas of the solder joints were investigated with a scanning electron microscope using the BSE modus (back scattered electron). Using metallization type A at a reflow temperature of 280°C the Sn-rich eutectic (e Fig. 8, top) was obrved. Often cracks appear directly after cooling
accepting
down to room temperature (e Fig. 8, top). With incread Au content (metallization type B) at a higher reflow temperature at 240°C the Au-richer intermetallic phas AuSn2 and AuSn were obrved. In Fig. 9 a cross ction of a flip-chip LED after reflow at 240°C is shown. Using metallization type C at a reflow temperature of 290°C a typical Au80Sn20 interface was obtained (e Fig. 10). Becau the Au was offered from chip and substrate side the eutectic Au80Sn20 is obrved between ζ pha layers growing on chip and substrate interface (e Fig. 11). Reliable ζ-pha interconnection where achieved in a wide parameter range (325-350°C) with the bumped LED (metallization type D).
Reliability英语免费学习网站
怎样撒娇
The reliability of the solder joint formed by tin-rich and gold-rich eutectic AuSn solder was compared earlier [3]. Here we focus on the comparison between gold-rich interfaces of the metallization type C  and D . The shear values of the bumped LEDs (metallization type D ) are significant higher than the shear values of metallization type C. For the layout C different shear modes were obrved (chip breaking, partly solder joint, pad lift on substrate side). Sometimes not all three Au contacts of the LED were wetted by the tin. Becau the tin pads were undersized a competition between wetting of the full Au substrate pad and wetting of the LED Au contact proceed. In contrast, for the layout D sol
ely chip breaking was obrved and the values are between 400cN and 900cN. This is due to the improved wetting situation of the layout C .
The yield of the solder process is better than 98% using solder temperatures between 325°C and 350°C. Over 50 LEDs were aged for 120h or 240h at 200°C or cycled between -40°C and +150°C for 500 times. Neither the voltage drop incread nor the luminance decread for any LED and the shear values were within the normal range. Due to the formation of Kirkendall voids it was obrved earlier that the tin caps of AuSn electroplated bumps fall off if no reflow is performed. For the FC-LED we could show that the reflow step can be omitted and LED wafer were ud that were plated more than three month before asmbly without a
decrea of yield and shear values.
Fig. 10 BSE picture of a solder joint of the LED. (C,290°C). The connection is formed by the
eutectic Au80Sn20. ζ pha layers (bright pha) grow at the chip and at the substrate side.
f
Fig. 11 BSE picture of an interconnection of a LED (D , 350°C) formed by the ζ pha.
Conclusions and Outlook
A low cost FC-process was developed for soldering the electric contacts of LEDs with Au80Sn20 suited to the plating process of EPIGAP. The automatic pick and place process was investigated. On a apm2200 from Datacon a throughput of 3 s/units could be achieved.
It was shown that reliable Au80Sn20 solder joints can be achieved with ζ-pha layers formed on the substrate and on chip side. Pure ζ-pha interconnections are formed in ca of sufficient Au-excess.
For bumped LEDs a very reliable solder process was established with a high yield (better than 98%) and a wide process window.
The next step will be the transfer of the wafer level process from silicon wafers to ceramic wafers. Bumped FC-LEDs were soldered on single ceramic carriers which can be individualized just by breaking. The ceramic LED carrier will have the advantage of through connection and the components will function as real SMD devices (e
Fig. 12).
Fig. 12 LED on a ceramic carrier

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