英文资料来源于EPA方法502.2,根据笔者自己的理解进行翻译,不当之处,欢迎指正。
3.1 Intern al Standa rd (IS) -- A pure analyt e(s) addedto a soluti on in knownamount(s) and ud to measur e the relati ve respon s of othermethod analyt es and surrog atesthat are compon entsof the same soluti on. The intern al standa rd must be an analyt e that is not a sample compon ent.
内标物(IS)——将一个已知质量,样品中不含有杂质的纯物质,加入至待测样品溶液中,以此纯物质的量为标准,对比测定待测组分的含量,该纯物质称为内标物。
内标物需满足下列要求:能完全溶解于样品中,且不与待测组分发生化学作用;峰位尽可能与待测组分的峰位靠近,但能与待测组分完全分开(分离度R≥1.5)的纯物质。若得不到纯品,必须预先测定其准确含量,且杂质峰不得干扰待测组分峰。内标物有时不易寻找是内标法的缺点。
娃娃脸男生3.2 Surrog ate Analyt e (SA) -- A pure analyt e(s), whichis extrem ely unlike ly to be foundin any sample, and whichis addedto a sample aliquo t in knownamount(s) before extrac tionand is measur ed with the same proced uresud to measur e othersample compon ents. The purpos e of a surrog ate analyt e is to monito r method perfor mance with each sample.
替代标准物(SA)——某种在任何样品中都不会出现的分析物,加入已知量的该替代标准物到一份等分
样品中(在提取前),和其他其他被分析物用同样的步骤测定。用于监测其回收率来评价整个前处理过程的有效性。
3.3 Labora toryDuplic ates(LD1 and LD2) -- Two sample aliquo ts takenin the analyt icallabora toryand analyz ed para telywith identi cal proced ures. Analys es of LD1 and LD2 give a measur e of the precis ion associ atedwith labora toryproced ures, but not with sample collec tion, prer vatio n, or storag e
proced ures.
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实验室平行——两份等分样品,分别在实验室中进行相同步骤的分析。对LD1和L D2的分析对实验室分析过程的精密度的评价,但是不包括样品的收集、保存和储存过程。
3.4 FieldDuplic ates(FD1 and FD2) -- Two para te sample s collec ted at the same time and placeunderidenti cal circum stanc es and treate d exactl y the same throug houtfieldand labora toryproced ures.
Analys es of FD1 and FD2 give a measur e of the precis ion associ atedwith sample collec tion,
prer vatio n and storag e, as well as with labora toryproced ures.
采样平行(FD1,FD2)——两份在相同环境下同一时间同一地点独立采样的样品,并使用同样的当场处理和实验室处理。对FD1和F D2的分析评价采样过程、保存和储存过程以及实验室分析过程的精密度。
3.5 Labora toryReagen t Blank(LRB) -- An aliquo t of reagen t waterthat is treate d exactl y as a sample includ ing exposu re to all glassw are, equipm ent, solven ts, reagen ts, intern al standa rds, and surrog atesthat are ud with othersample s. The LRB is ud to determ ine if method analyt es or otherinterf erenc es are pren t in the labora toryenviro nment, the reagen ts, or the appara tus.
实验室试剂空白(LRB)——一份试剂水用和样品相同的方法进行处理,包括暴露于玻璃容器,仪器,溶剂,试剂,内标物,替代标准物等,用于确定方法分析物或其他干扰因素是否存在于实验室环境、试剂和仪器中。
3.6 FieldReagen t Blank(FRB) -- Reagen t waterplaced in a sample contai ner in the labora toryand
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treate d as a sample in all respec ts, includ ing exposu re to sampli ng site condit ions, storag e, prer vatio n and all analyt icalproced ures. The purpos e of the FRB is to determ ine if method analyt es or other
interf erenc es are pren t in the fieldenviro nment.
初级药师报名时间采样试剂空白(FRB)——试剂水在实验室置于采样容器中,和其他样品用相同方法处理,包括暴露于采样环境中,储存,保存和其他分析过程。用于确定方法分析物或其他干扰因素是否存在于采样环境中。
3.7 Labora toryPerfor mance CheckSoluti on (LPC) -- A soluti on of method analyt es, surrog ate
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实验室柱效检测溶液(LPC)——包括方法分析物,替代标准舞和内标的溶液,用于评价仪器系统的情况是否符合方法要求。
3.8 Labora toryFortif ied Blank(LFB) -- An aliquo t of reagen t waterto whichknownquanti tiesof the method analyt es are addedin the labora tory. The LFB is analyz ed exactl y like a sample, and its purpos e is to determ ine whethe r the method ology is in contro l, and whethe r the labora toryis capabl e of making accura te and precis e measur ement s at the requir ed method detect ion limit.
实验室强化空白(LFB)——一份等分试剂水,在实验室中被添加已知量的方法分析物。LFB和样品一样进行分析,目的是为了确定方法学是否处于受控状态,此实验室是否能够在此方法的检测限下做出准确和精密的分析。
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3.9 Labora toryFortif ied Sample Matrix (LFM) -- An aliquo t of an enviro nment al sample to whichknownquanti tiesof the method analyt es are addedin the labora tory. The LFM is analyz ed exactl y like a sample, and its purpos e is to determ ine whethe r the sample matrix contri butes bias to the analyt icalresult s. The backgr oundconcen trati ons of the analyt es in the sample matrix must be determ inedin a para te aliquo t and the measur ed values in the LFM correc ted for backgr oundconcen trati ons.
实验室强化样品基质(LFM)——一份等分环境样品,在实验室中被添加已知量的方法分析物。LFM和样品一样进行分析,目的是为了确定样品基质对分析结果的影响。在样品基质中分析物的背景值能够从一份独立的样品和LF M的检测值的修正来确定。
3.10 StockStanda rd Soluti on -- A concen trate d soluti on contai ninga single certif ied standa rd that is a method analyt e, or a concen trate d soluti on of a single analyt e prepar ed in the labora torywith an assaye d refere nce compou nd. Stockstanda rd soluti ons are ud to prepar e primar y diluti on standa rds.
储备标准溶液——含有一定浓度的单个方法分析物的溶液,其浓度值是经过确认的(指直接购买的);或是在实验室中用经过确认的标准品配制成一定浓度的单个方法分析物的溶液(实验室自己配制)。储备标准溶液是用于配制第一稀释标准溶液。
3.11 Primar y Diluti on Standa rd Soluti on (PDS) -- A soluti on of vera l analyt es prepar ed in the labora toryfrom stockstanda rd soluti ons and dilute d as needed to prepar e calibr ation soluti ons and otherneeded analyt e soluti ons.
第一稀释标准溶液(PDS)——在实验室中由储存标准溶液配制的含有多种方法分析物的标准溶液,可以根据需要配制成校准溶液或其他所需分析物溶液。
3.12 Calibr ation Standa rd (CAL) -- A soluti on prepar ed from the primar y diluti on standa rd soluti on and stockstanda rd soluti ons of the intern al standa rds and surrog ate analyt es. The CAL soluti ons are ud to calibr ate the instru mentrespon with respec t to analyt e concen trati on.
校正曲线标准溶液(CAL)——从第一稀释溶液或内标物和替代标准物的储存溶液配制的溶液。校正曲线标准溶液用于制作仪器相应和分析物浓度相关的标准曲线。
曲面屏有什么好处3.13 Qualit y Contro l Sample (QCS) -- A sample matrix contai ningmethod analyt es or a soluti on of method analyt es in a watermiscib le solven t whichis ud to fortif y reagen t wateror enviro nment al sample s. The QCS is obtain ed from a source extern al to the labora tory, and is ud to checklabora toryperfor mance with extern allyprepar ed test materi als.
质量控制样品(QCS)——一份包含了方法分析物的基质样品;或是含有方法分析物的溶液(其溶剂是可以和水互溶的)加入到强化试剂水中或是环境样品中。质量控制样品是从实验室外部获得,用于通过外部准备的测试样品来检查实验室的检测能力。
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3.14 Proced uralStanda rd Calibr ation -- A calibr ation method whereaqueou s calibr ation standa rds are prepar ed and proces d (e.g., purged,extrac ted, and/or deriva tized) in exactl y the same manner as a sample. All stepsin the proces s from additi on of sampli ng prer vativ es throug h instru menta l analys es
are includ ed in the calibr ation. Usingproced uralstanda rd calibr ation compen sates for any ineffi cienc ies in the proces singproced ure.
程序标准校准——将校准标准和样品相同的方法进行准备和处理(如吹扫,萃取或衍生)的校准方法。程序中所有步骤,包括从采样保存添加到仪器分析都包括在此校准中。用程序标准校准来补偿在前处理过程的低效。