CAUTIONARY RESPONSE INFORMATION Common Synonyms Watery liquid Colorless Extremely
irritating odor
Sinks in water. Flammable, irritating vapor is produced.
Allyl chlorocarbonate
Stop discharge if possible. Keep people away.
Shut off ignition sources. Call fire department.
Avoid inhalation.
Isolate and remove discharged material.
Notify local health and pollution control agencies.
Protect water intakes.
Fire FLAMMABLE
Flashback along vapor trail may occur.
Vapor may explode if ignited in an enclod area.
Wear goggles, lf-contained breathing apparatus and rubber可爱的小蛋糕
overclothing (including gloves).
Extinguish with dry chemicals, foam or carbon dioxide.
Water may be ineffective on fire.
Cool expod containers with water.
Exposure Call for medical aid.
VAPOR
Irritating to eyes, no and throat.
If inhaled will cau difficult breathing.
Move victim to fresh air.
If breathing is difficult, give oxygen.
LIQUID
Irritating to skin and eyes.
Harmful if swallowed.
Remove contaminated clothing and shoes.
Flush affected areas with plenty of water.
IF IN EYES, hold eyelids open and flush with plenty of water.
IF SWALLOWED and victim is CONSCIOUS, have victim drink water
or milk.
Water Pollution Effect of low concentrations on aquatic life is unknown. May be dangerous if it enters water intakes.
Notify local health and wildlife officials.
Notify operators of nearby water intakes.
1. CORRECTIVE RESPONSE ACTIONS
Dilute and disper small amounts
Stop discharge
Collection Systems: Pump; Dredge
Chemical and Physical Treatment:
Neutralize
2. CHEMICAL DESIGNATIONS
2.1 CG Compatibility Group: Not listed
2.2 Formula: CH2=CH.CH2.O.COCl
2.3 IMO/UN Designation: 8/1722
2.4 DOT ID No.: 1722
2.5 CAS Registry No.: 2937-50-0
2.6 NAERG Guide No.: 155
2.7 Standard Industrial Trade Classification:
51374
3. HEALTH HAZARDS
3.1 Personal Protective Equipment: Vapor-proof protective goggles and face shield; plastic or rubber
gloves, shoes and clothing; gas mask or lf-contained breathing apparatus.
3.2 Symptoms Following Exposure: Vapor irritates eyes and respiratory tract. Contact with liquid
caus eye and skin irritation, and ingestion irritates mouth and stomach.
3.3 Treatment of Exposure: INHALATION: remove from exposure; support respiration if necessary; call
physician. EYES: if irritated by either vapor or liquid, flush with water for at least 15 min. SKIN: wash with large amounts of water for at least 15 min. INGESTION: do NOT induce vomiting; give water; call physician.
3.4 TLV-TWA: Not listed.
3.5 TLV-STEL: Not listed.
3.6 TLV-Ceiling: Not listed.
3.7 Toxicity by Ingestion: Grade 3; LD50 = 50 to 500 mg/kg
3.8 Toxicity by Inhalation: Currently not available.
3.9 Chronic Toxicity: Currently not available
3.10 Vapor (Gas) Irritant Characteristics: Vapors are moderately irritating such that personnel will not
usually tolerate moderate or high vapor concentrations.
3.11 Liquid or Solid Characteristics: Fairly vere skin irritant. May cau pain and cond-degree
burns after a few minutes' contact.
3.12 Odor Threshold: 1.4 ppm
3.13 IDLH Value: Not listed.
3.14 OSHA PEL-TWA: Not listed.
3.15 OSHA PEL-STEL: Not listed.
3.16 OSHA PEL-Ceiling: Not listed.
3.17 EPA AEGL:Not listed
4. FIRE HAZARDS
4.1 Flash Point: 92°F O.C. 88°F C.C.
4.2 Flammable Limits in Air: Currently not
available
4.3 Fire Extinguishing Agents: Dry
chemical, foam, carbon dioxide
4.4 Fire Extinguishing Agents Not to Be
Ud: Water may be ineffective
4.5 Special Hazards of Combustion
Products: When heated to
decomposition, emits highly toxic
phosgene gas.工业粘合剂
4.6 Behavior in Fire: Vapor is heavier than
air and may travel considerable distance
to a source of ignition and flash back.
4.7 Auto Ignition Temperature: Currently not
available
4.8 Electrical Hazards: I, D
4.9 Burning Rate: 4.9 mm/min.
4.10 Adiabatic Flame Temperature: Currently
not available
4.11 Stoichometric Air to Fuel Ratio:
Currently not available
4.12 Flame Temperature: Currently not
available
4.13 Combustion Molar Ratio (Reactant to
Product): Currently not available
4.14 Minimum Oxygen Concentration for
Combustion (MOCC): Not listed
5. CHEMICAL REACTIVITY
5.1 Reactivity with Water: Reacts slowly,
generating hydrogen chloride.
5.2 Reactivity with Common Materials:
Corrodes metals
5.3 Stability During Transport: Stable
5.4 Neutralizing Agents for Acids and
Caustics: Flush with water, rin with
lime or sodium bicarbonate solution.
5.5 Polymerization: Currently not available.
5.6 Inhibitor of Polymerization: Not pertinent
6. WATER POLLUTION
6.1 Aquatic Toxicity:
Currently not available
6.2 Waterfowl Toxicity: Currently not
available
6.3 Biological Oxygen Demand (BOD):
Currently not available
6.4 Food Chain Concentration Potential:
None
6.5 GESAMP Hazard Profile:
Bioaccumulation: 0
Damage to living resources: -
Human Oral hazard: 2
Human Contact hazard: II
Reduction of amenities: XXX
7. SHIPPING INFORMATION
7.1 Grades of Purity: Commercial, 97+%
7.2 Storage Temperature: Keep cool
7.3 Inert Atmosphere: No requirement
7.4 Venting: Pressure-vacuum
7.5 IMO Pollution Category: Currently not available
7.6 Ship Type: Currently not available
7.7 Barge Hull Type: Currently not available
8. HAZARD CLASSIFICATIONS
8.1 49 CFR Category: Poison
8.2 49 CFR Class: 6.1
8.3 49 CFR Package Group: I
8.4 Marine Pollutant: No
8.5 NFPA Hazard Classification:
Category Classification
Health Hazard (Blue) (3)
Flammability (Red) (3)
Instability (Yellow) (1)
8.6 EPA Reportable Quantity: Not listed
8.7 EPA Pollution Category: Not listed
8.8 RCRA Waste Number: Not listed
8.9 EPA FWPCA List: Not listed
9. PHYSICAL & CHEMICAL
PROPERTIES
9.1 Physical State at 15° C and 1 atm: Liquid
9.2 Molecular Weight: 120.5
9.3 Boiling Point at 1 atm: 235°F = 113°C =
386°K
9.4 Freezing Point: –112°F = –80°C = 193°K
9.5 Critical Temperature: Not pertinent
9.6 Critical Pressure: Not pertinent
9.7 Specific Gravity: 1.139 at 20°C (liquid)
9.8 Liquid Surface Tension: (est.) 25 dynes/cm
= 0.025 N/m at 20°C
9.9 Liquid Water Interfacial Tension: Not
pertinent
9.10 Vapor (Gas) Specific Gravity: 4.15
9.11 Ratio of Specific Heats of Vapor (Gas):
1.0804
9.12 Latent Heat of Vaporization: (est.) 100
Btu/lb = 56 cal/g = 2.3 X 105 J/kg
9.13 Heat of Combustion: (est.) –7,800 Btu/lb =
–4,300 cal/g = –180 X 105 J/kg
9.14 Heat of Decomposition: Not pertinent
9.15 Heat of Solution: Not pertinent
9.16 Heat of Polymerization: Not pertinent
9.17 Heat of Fusion: Currently not available
9.18 Limiting Value: Currently not available
9.19 Reid Vapor Pressure: Currently not
available
NOTES
ALLYL CHLOROFORMATE ACF
9.20
SATURATED LIQUID DENSITY
Temperature
(degrees F)
Pounds per cubic foot
34 36 38 40 42 44 46 48 50 52 54 56 58 60 62 64 66 68 70 72 74 76 78 80 82 84
72.339
72.270
72.200
72.129
72.059
71.990
71.919
71.849
71.790
71.719
71.650
71.580
71.509
71.440
71.370
71.299
71.230
71.160
71.089
71.020
70.950
70.879
70.809
70.750
70.679
70.610
9.21
哎呀我的妈呀LIQUID HEAT CAPACITY
Temperature
(degrees F)
British thermal unit per
pound-F
34
36
38
40
42
44
46
48
50
52
54
56
58
60
62
64
66
68
70
72
74
76
78
80
82
84
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
0.450
9.22
LIQUID THERMAL CONDUCTIVITY
Temperature
(degrees F)
British thermal unit inch
per hour-square foot-F
34
36
38
40
42
44
46
48
50
52
54
56
58
60
62
64
66
68
70
72
74
76
78
80
82
84
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
1.048
9.23
LIQUID VISCOSITY
Temperature
(degrees F)
Centipoi
34
36
38
40
42
44
46
48
50
52
54
56
青岛旅游必去景点
58
60
62
64
66
68
70
72
74
76
78
80
散打教学与训练82
84
0.958
0.940
0.923
0.906
0.889
0.873
0.858
0.842
0.827
0.813
0.799
0.785
0.772
0.758
0.746
0.733
0.721
0.709
0.698
0.686
0.675
0.664
0.654
0.644
0.633
焗饭的做法0.624 9.24
SOLUBILITY IN WATER
Temperature (degrees F)Pounds per 100 pounds
of water
I
N
S
O
L
U
B
L
E
9.25
SATURATED VAPOR PRESSURE
Temperature环游世界八十天
(degrees F)
Pounds per square inch
60
65
70
75
80
85
90
95
100
105
110
115
120
4.950
5.538
6.182
6.888
7.658
8.498
9.413
10.410
11.480
12.650
13.910
15.280
16.750
9.26
SATURATED VAPOR DENSITY
Temperature
(degrees F)
Pounds per cubic foot
60
65
70
75
80
85
90
95
100
105
110
115
120
0.10690
0.11850
0.13100
0.14460
0.15930
0.17510
0.19220
0.21060
0.23030
0.25150
0.27420
0.29840
0.32430
9.27
IDEAL GAS HEAT CAPACITY
Temperature
(degrees F)
British thermal unit per
pound-F
100
120
140
160
180
200
220
240
260
280
300
320
340
360
380
400
420食品安全管理
440
0.230
0.236
0.241
0.247
0.252
0.257
0.263
0.268
0.273
0.278
0.284
0.289
0.294
0.299
0.304
0.309
0.314
0.319
