示踪剂知识

更新时间:2023-05-19 19:05:43 阅读: 评论:0

心情低落图片一,井间示踪剂技术概述:
(1) 注水开发后期油田特征
注水开发的油田,由于油藏平面和纵向上的非均质性以及油水粘度的差别及注采井组内部的不平衡,势必造成注入水在平面上向生产井方向的舌进现象和在纵向上向高渗透层的突进现象。特别是在注水开发后期,油井含水高达90%以上,由于注入水的长期冲刷,油藏孔隙结构和物理参数将会发生较大变化,在注水井和油井之间有可能产生特高的渗透率薄层,流动孔道变大,造成注入水在注水井和生产井之间的循环流动,大大降低了水驱油的效率。为了提高水驱油效率,目前提出了各种治理措施,如注水井调剖,油井堵水,打调整井和用水动力学方法改变液流方向等。而这些措施是否有效,关键是对油藏的认识程度,从而提出要对油藏进行精细描述,井间示踪剂测试便是为这一目的而提出来的。
(2) 示踪剂类型及特征
示踪剂是指那些能随注入流体一起流动,指示流体在多孔介质中的存在、流动方向和渗流速度的物质。示踪剂的种类较多,按其化学性质可分为化学示踪剂和放射性示踪剂;按其溶解性质可分为分配性示踪剂和非分配性示踪剂。
化学示踪剂常见的有:离子型,如SCN-、NO3-、Br-、I-等;有机类,如甲醛、乙醇、异丙醇等;染料类和惰性气体;放射性示踪剂常见的有:氚水、氚化正丁醇、氚化乙醇等。
非分配性示踪剂只溶于水;而分配性示踪剂既溶于水,又溶于油,但在油、水中的分配比例不同。
一种好的示踪剂应满足以下条件:
① 油层中背景浓度低;
② 油层中滞留量少;
③ 化学稳定、生物稳定、与地层流体配伍;
④ 分析操作简单,灵敏度高;
⑤ 无毒、安全;
⑥ 来源广、成本低;
(3) 井间示踪剂监测。
井间示踪剂测试是从注水井注入示踪剂段塞,从周围生产井中检测其产出情况并绘出示踪
剂产出曲线。通过对井间示踪剂产出曲线的分析来确定井间地层参数,并求出剩余油饱和度的分布。
井间示踪剂测试时,如果同时注入一种分配性示踪剂和一种水溶性示踪剂,由于这两种示踪剂的油溶性差别较大,水溶性示踪剂只溶于水,产出早;而分配性示踪剂既溶于水又溶于油,产出晚。根据两种示踪剂的产出时间差和分配系数,即可求得剩余油饱和度。
除井间示踪剂测试外,还有单井示踪剂测试,即从同一口井注入和采出示踪剂来测定剩余油饱和度的方法。通常是把低分子的酯作为第一示踪剂注入后,遇水分解,生成一种醇作为第二示踪剂。这两种示踪剂在油水中的分配系数不同,第一种示踪剂是亲油的,第二种示踪剂是亲水的。两种示踪剂在回采时发生分离,其峰值到达地面有一个时间差,根据该时间差即可求得剩余油饱和度。
井间示踪剂监测的目的
(1) 分析油藏在平面和纵向上的非均质情况;
(2) 判断地层中是否存在高渗透层,求出其厚度、渗透率等地层参数;
(3) 确定调剖剂
(4) 求出目前地下高渗透层及其它厚层的剩余油饱和度分布。
二,井间示踪剂常用分析方法:
放射性同位素:用液相闪烁计数器测定放射性活度
非放射性同位素:中子活化法,γ能谱仪等测定
气体示踪剂:气体正比计数器测定:高放射性活度63Ni电子捕获技术
化学示踪剂:分光光度法,色谱分离法
微量物质示踪剂:ICP—MS或者LS-MS分析法 深圳好玩的景点
追问:
这些我都知道,主要是具体的原理,操作步骤,计算方法。比如说,化学示踪剂里有水溶性示踪剂,其中常用的有硫氰酸胺,亚硝酸钠,硝酸钠,有机磷酸盐等等,每种示踪剂又有不同的原理,操作步骤,计算方法,以及适用范围,和优缺点。你说的这些太泛。
回答:
1,井间示踪原理 :
从监测注入井注入示踪剂段塞 感谢朋友的话
在周围目标生产井取样分析,监测其产出情况,绘出示踪剂产出曲线
根据油藏动静态分析方法,利用专门解释工具,对示踪监测信息进行分析、处理和解释,定量或者定性的认识油藏井间、层间、层内和油水井周围的静态、动态信息
在此基础上,进一步完成油藏重新地质建模、得到特征参数变化规律、进行数值模拟校正和完善、评价措施开发效果、设计措施工艺参数等。
2,如果你想知道具体的操作步骤,使用方法,建议你参考以下的资料:
用井间示踪方法确定剩余油饱和度分布信息编号:KJGLB2009061419352 发布日期: 2009-06-14 截止日期: 不限 地区:日照
数鸭子歌词
名称:
用井间示踪方法确定剩余油饱和度分布
联系人:
安彦
地址:
邮编:
荻浦花海电话:
0633-8799168
传真:
0633-2221116
Email地址:
发布时间
2009-6-13
情况简介:
研究内容如下:a
1. 评价油藏非均质性,包括井间连通性、平面及纵向非均质性、方向渗透性及大孔道等,为调剖堵水提供依据。
2. 确定指标:井网的体积波及系数、水淹层的厚度及渗透率的大小、平均孔道半径、流体饱和度、井网注采指标和油藏岩石的润湿性。
3. 核实断层及封闭性。
兰花品种4. 根据相邻层系井的示踪剂产出情况,判断射孔和层系间隔层性质,为层系细分调整提供依据。
5. 分析开发调整措施的有效程度。
井间示踪剂方法是一种确定井间地层参数分布较为先进的技术。其技术含量高,理论研究基础扎实,解释参数可靠。油田中广泛使用的示踪剂主要用来确定井间连通性与渗透率的变异情况,这对油田的开发调整、挖潜和三次采油的开展,具有重要的价值。
Techniques available include Gas Chromatography, GCMS, GCMS-Triple Quad, Liquid Scintillation, Thermal Desorption, IC and HPLC.
proven chemical tracers, which are stable under rervoir conditions, resist biodegradation and are passive to formation and other fluids within the rervoir.
Czechoslovak Journal of Physics
1999, Volume 49, Issue 1 Supplement, pp 861-866
最字草书
Publisher
International Petroleum Technology Conference
Language
English
Document ID
15312-MS
DOI
10.2523/15312-MS
Content Type
Conference Paper
Title
Fluorescent Nanobeads: A New Generation of Easily Detectable Water Tracers
Authors
Nicolas Agenet; Navid Moradi-Tehrani, Total Olivier Tillement, Université Lyon I
Source
International Petroleum Technology Conference, 7-9 February 2012, Bangkok, Thailand
ISBN
978-1-61399-148-0
Copyright
2011. International Petroleum Technology Conference
Discipline
Categories
6.6 Rervoir Monitoring/Formation Evaluation
6.6.8 Tracers
Preview
牧童之歌
Abstract
Rervoir monitoring is an esntial tool to optimize oil production. Among other techniques, water tracers are very uful to understand complex flow patterns that may ari between injection and production wells during waterflood operations. This paper propos an innovative approach for developing new fluorescent tracers bad on silica nanoparticles; it describes their synthesis and properties during coreflood experiments.

The new nanoparticles can be coded with various fluorophores, which can be easily detected using on-site equipment offering direct tracer quantification and even on-line monitoring capabilities.

Silica nanoparticles containing one or more organic dyes or lanthanide-bad fluorophores were synthesized. The versatility of the synthesis procedure allows coding the nanoparticles with theoretically dozens of tagging combinations. The sol-gel synthesis technique yields 50-nm-diameter nanoparticles which are treated to tune their surface properties. The conrvative tracer behavior of such nanoparticles is ensured by proper surface functionalization, and is demonstrated by coreflood experiments. This virtually large tracer library is combined to a unique time-delay fluorescence detection technique which allows simple on-site tracer quantification on multiple nanoparticle types with minimal sample preparation.

Introduction
InterWell Tracer Tests (IWTT) are routinely ud in the petroleum industry (Du and Guan 2005). This technique allows gathering informations on well-to-well connections and subsurface flow paths. Aqueous tracers can be split in two main groups upon their function: passive tracers which travel at the same velocity as the injected water and partitioning tracers which are partly soluble in oil, leading to a delay in their breakthrough. Ud along with passive tracers, partitioning tracers permit to evaluate the remaining oil saturation in the contacted zone (Tang 1991, Tang, 1992, Tang 1995, Wood 1990, Deeds 2000, Dwarakanath 1999, Jin 1995, Jin 1997, Mariner 1999). Tracers can be lected in the following families: naturally occurring tracers (isotopic or ionic composition footprints), radioactive isotopes, and chemical derivatives (Du and Guan 2005, Hutchins 1991). Each family posss its own advantages and limitation: restricting regulation on radioactive tracers can make them difficult to implement on field in some areas; chemical tracers such as fluorobenzoic acids (FBAs) have become routinely ud for field tracer campaigns as they can be detected with a low detection limit. However they require fine analys which cannot be performed in standard labs. Moreover, in each family the number of available chemical tracers remains limited when repeated tracer campaigns are required on the same field over time.

This paper describes the design of nanoparticles as tracers and coreflood tests to asss their propagation in porous media. Rare-earth bad organometallic complexes are known to posss a long fluorescence lifetime. A low detection limit of the nanoparticles can be achieved by incorporating such complexes. Taking advantage of the fluorescence lifetime differences, background fluorescence from organic oil contaminant of the sample is suppresd using time-resolved fluorescence detection. The nanobeads associate the transport behavior of nanoparticles in porous media with the fluorescence properties of rare-earth elements complexes to give access to easily detectable passive tracer.

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