蛊师Synthesis of Diver γ-Aryl-β-ketoesters via Aryne Intermediates Generated by C-C Bond Cleavage.
期刊名称： Organic letters
毕飞宇
详细的英语作者： Keisuke,Uchida,Yasunori,Minami,Suguru,Yoshida,Takamitsu,Hosoya
作者机构： Laboratory
年份： 2019年
红烧小鸡腿
大理有什么好玩的地方景点推荐期号： 第22期
摘要：A synthetic method for diver γ-aryl-β-ketoesters through γ-aryl-β-ketoester-type arynes triggered by C-C bond cleavage has been developed. The Mukaiyama aldol reaction of 6-(triflyloxy)benzocyclobutenones with ketene silyl acetals and subquent treatment of resulting 6-(triflyloxy)benzocyclobutenols with a ba triggered the efficient generation of γ-aryl-β-ketoester-type arynes, which reacted with various arynophiles to provide a wide range of γ-aryl-β-ketoesters. The synthetic utility of the method was demonstrated by the synthesis of an analog of ALK inhibitor.一节课的英文
班级现状分析>学蒸馒头
内容由中国教育图书进出口有限公司引进
