MERGAL K10N
Identification of the substance/preparation and of the company/undertaking
+32 (0) 14 58 45 45
SAFETY DATA SHEET
Product name
MERGAL K10N
滑冰车Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Asia
1.Emergency telephone number :TROY CHEMICAL EUROPE BV
Uiverlaan 12e PO Box 132
3145 XN Maassluis The Netherlands
Phone: + 31 (0) 10 592-7494Manufacturer
::Application:
:In-can prervative for amongst others: polymer dispersions, paints, adhesives and thickener solutions.
瓜果飘香造句
Prepared by
: B.J. Vernooij, SDS Specialist ()
Supplier Asia
:Building, 11th floor,
120 Moo 11, Bangna Trad,bangna, Bangkok 10260,Thailand
Phone: +662 - 3973721 to 6Fax: +662 - 3973729
Emergency Contact name:Yaiyana Jipiphop-Customer Service Manager
tel: 662-3973721-6 ext: 108Hand Phone: 66-818323702Uraiwan Photichai-Logistics Manager
tel: 662-3973721-6 ext: 109Hand Phone: 66-892055951
Hazards identification
2.Classification :The product is classified as dangerous according to Directive 1999/45/EC and its amendments.Human health hazards :Effects and symptoms
Signal word Danger
:Classification
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1AQUATIC TOXICITY (ACUTE) - Category 2
:
Toxic to aquatic life.
Composition/information on ingredients
3.Substance/preparation Preparation
Occupational exposure limits, if available, are listed in ction 8.:CAS no.%EC number Classification Chemical name*
Benzisothiazol- 3(2h)-one
2634-33-5
7 - 10
220-120-9
Xn; R22
Xi; R41, R38R43N; R50[1]
Potassium Hydroxide
1310-58-3 3 - 5215-181-3
Xn; R22C; R35
[1]
[2]
See ction 16 for the full text of the R-phras declared above大字开头的成语
[1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit
Expected GHS Classification for the ingredients (* See notice to reader in Section 16).2634-33-5Xn; R22Xi; R41, R38R43N; R50ACUTE TOXICITY: ORAL - Category 4
SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION -Category 1SKIN SENSITIZATION - Category 1
AQUATIC TOXICITY (ACUTE) - Category 1
Potassium Hydroxide 1310-58-3Xn; R22C; R35ACUTE TOXICITY: ORAL - Category 4
SKIN CORROSION/IRRITATION - Category 1A
Chemical name*CAS no.EU Classification GHS Classification Get medical attention immediately. Wash out mouth with water. Remove dentures if any. Move expod person to fresh air. Keep person warm and at rest. If material has been swallowed and the expod person is conscious, give small quantities of water to drink. Stop if the expod person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to
an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loon tight clothing such as a collar, tie, belt or waistband.Skin contact
Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lens. Continue to rin for at least 10 minutes. Chemical burns must be treated promptly by ving it, or wear gloves. Continue to rin for at least 10 minutes. Chemical burns must be treated promptly by a ph
ysician. Wash clothing before reu. Clean shoes thoroughly before reu.4.First aid measures Get medical attention immediately. Move expod person to fresh air. If it is suspected that fumes李隆
are still prent, the rescuer should wear an appropriate mask or lf-contained breathing apparatus.Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs,provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loon tight clothing such as a collar,tie, belt or waistband. In ca of inhalation of decomposition products in a fire, symptoms may be delayed. The expod person may need to be kept under medical surveillance for 48 hours.No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still prent, the rescuer should wear an appropriate mask or lf-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Protection of first-aiders
Ingestion
Inhalation
Eye contact
:::::First aid measures
Suitable
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Decomposition products may include the following materials:carbon dioxide carbon monoxide nitrogen oxides sulfur oxides
metal oxide/oxides
Fire-fighters should wear appropriate protective equipment and lf-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Protection of fire-fighters
Special fire-fighting procedures Extinguishing media ::::U an extinguishing agent suitable for the surrounding fire.
Unusual fire/explosion hazards :In a fire or if heated, a pressure increa will occur and the container may burst.Personal precautions
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (e ction 8).6.Accidental relea measures
:Note: e ction 8 for personal protective equipment and ction 13 for waste disposal.
Environmental precautions
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and wers.Inform the relevant authorities if the product has caud environmental pollution (wers, waterways,soil or air).
Methods for cleaning up
:Stop leak if without risk. Move containers from spill area. Approach relea from upwind. Prevent entry into wers, water cours, baments or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (e ction 13). Dispo of via a licend waste disposal contractor.Contaminated absorbent material may po the same hazard as the spilled product. Note: e ction 1 for emergency contact information and ction 13 for waste disposal.
Handling
Handling and storage
Storage
7.wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing.Do not breathe vapor or mist. Do not ingest. If during normal u the material prents a respiratory hazard, u only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly clod when not in u. Keep away from acids. Empty containers retain product residue and can be hazardous. Do not reu container.
Packaging materials U original container.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (e ction 10) and food and drink. Separate from acids. Keep container tightly clod and aled until ready for u.Containers that have been opened must be carefully realed and kept upright to prevent leakage.Do not store in unlabeled containers. U appropriate containment to avoid environmental contamination.:::Recommended u
Ingredient name Occupational exposure limits Engineering measures
If ur operations generate dust, fumes, gas, vapor or mist, u process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits.
ACGIH TLV (United States, 1/2008). C: 2 mg/m³
8.Exposure controls/personal protection
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be ud to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are clo to the workstation location.
Hygiene measures
::Europe
Sweden
Recommended monitoring procedures
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to u respiratory protective equipment. Reference should be
made to European Standard EN 689 for methods for the asssment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.Skin and body
Personal protective equipment U a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk asssment indicates this is necessary. Respirator lection must be
bad on known or anticipated exposure levels, the hazards of the product and the safe working limits of the lected respirator.Personal protective equipment for the body should be lected bad on the task being performed
and the risks involved and should be approved by a specialist before handling this product.Respiratory system
CEIL: 2 mg/m³ Form: Inhalable dust
Arbejdstilsynet (Denmark, 3/2008). CEIL: 2 mg/m³
Arbeidstilsynet (Norway, 11/2007). CEIL: 2 mg/m³
INRS (France, 12/2007). Notes: indicative exposure limits
STEL: 2 mg/m³ 15 minute(s).
:::Denmark
Norway
France曾仕强解易经六十四卦
Lijst Grenswaarden / Valeurs Limites (Belgium, 6/2007). M: 2 mg/m³
Belgium
SUVA (Switzerland, 1/2007).
TWA: 2 mg/m³ 8 hour(s). Form: inhalable dust
Switzerland
GKV_MAK (Austria, 9/2007).
TWA: 2 mg/m³ 8 hour(s). Form: inhalable fraction
Austria
EH40/2005 WELs (United Kingdom (UK), 8/2007). STEL: 2 mg/m³ 15 minute(s).
United Kingdom (UK)
Työterveyslaitos, Sosiaali- ja terveysministeriö (Finland, 8/2007). CEIL: 2 mg/m³
Finland
Spain
INSHT (Spain, 1/2008).
STEL: 2 mg/m³ 15 minute(s).
Czech Republic
惬意近义词
178/2001 (Czech Republic, 12/2007). TWA: 1 mg/m³ 8 hour(s). STEL: 2 mg/m³ 15 minute(s).
Ireland
NAOSH (Ireland, 8/2007).
OELV-15min: 2 mg/m³ 15 minute(s).Estonia
Sotsiaalminister (Estonia, 10/2007). TWA: 2 mg/m³ 8 hour(s).Hungary
EüM-SzCsM (Hungary, 12/2007). TWA: 2 mg/m³ 8 hour(s).
PEAK: 2 mg/m³ 15 minute(s).
Poland
Ministra Pracy i Polityki Spo łecznej (Poland, 9/2007). TWA: 0.5 mg/m³ 8 hour(s). STEL: 1 mg/m³ 15 minute(s).Croatia
Ministry of Labor (KR, 6/2007). CEIL: 2 mg/m³
times when handling chemical products if a risk asssment indicates this is necessary.
Safety eyewear complying with an approved standard should be ud when a risk asssment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts.
Eyes
:>100°C (>212°F)
Physical and chemical properties
Physical state Boiling point工程概况模板
Vapor pressure Density Solubility
Liquid.
1.05 to 1.08 g/cm 3 [20°C (68°F)]
0 kPa (0 mm Hg)
Easily soluble in the following materials: cold water and hot water.
Characteristic.Odor pH
Yellowish. Brown.Color Flash point
Not available.
Non-explosive in the prence of the following materials or conditions: open flames, sparks and static discharge, heat, shocks and mechanical impacts, oxidizing materials, reducing materials,combustible materials, organic materials, metals, acids, alkalis and moisture.Non-flammable in the prence of the following materials or conditions: open flames, sparks and static discharge, heat, shocks and mechanical impacts, oxidizing materials, reducing materials,combustible materials, organic materials, metals, acids, alkalis and moisture.
Fire hazards in the prence of various substances 9.>12
Explosive properties
::::::::
:::Not available.
Oxidizing properties :Hazardous decomposition products
Conditions to avoid No specific data.
Stability and reactivity
Decomposition products may include the following materials:carbon dioxide carbon monoxide nitrogen oxides sulfur oxides
metal oxide/oxides菜的图片
The product is stable. Under normal conditions of storage and u, hazardous polymerization will not occur.
Stability
10.:::Toxicological information
Carcinogenic effects Eye irritation Skin irritation
Mutagenic effects
Corrosive to eyes. Caus burns.
11.Local effects
::::Teratogenic effects :Inhalation
:May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cau a health hazard. Serious effects may be delayed following exposure.
Ingestion
:May cau burns to mouth, throat and stomach.
Over-exposure signs/symptoms Target organs Contains material which caus damage to the followi
ng organs: lungs, upper respiratory tract, skin,
eye, lens or cornea.
:Sensitization: Buehler test (OECD 406, EU B.6): Not nsitizing
For the properties not tested with the formulated product, the results indicated in this ction are bad on the information available on the ingredients.
LD50 Dermal Rat >2000 mg/kg -LD50 Oral Mou 1150 mg/kg -LD50 Oral Rat 597 mg/kg -Potassium Hydroxide LD50 Oral Rat 273 mg/kg -MERGAL K10N
LD50 Dermal Rat >5000 mg/kg -LD50 Oral
Rat
>2000 mg/kg
-
Acute toxicity
Result
Species Do
Exposure Product name Classification Product name List name Name on list National regulations
