Synthesis and Characterization of A Nickel(II) Complex With Bis(Benzimidazol-2-Ylmethyl) (2-金属材料工程
珍珠熊
Hydroxyethyl)Amine
期刊名称： Journal of Coordination Chemistry
作者： Li-Hua,Yin,Ping-Yu,Bu,Peng,Cheng,Jing,Li,Shi-Ping,Yan,Zong-Hui,Jiang,Dai-Zheng,Liao
出谋献策
年份： 2010年阶段英文
text函数
期号： 第5期
关键词： Nickel(II) Complex;Crystal Structure;1,10-phenanthroline;2,2â²-
老蜜蜂bipyridine;Spectroscopy
摘要：This paper reports the synthesis, crystal structure and properties of two new mononuclear nickel(II) complexes, [NiL(phen)][ClO4]2(1) and [NiL(bpy)] [ClO4]2(2), where L is bis(benzimidazol-2-ylmetheyl)(2-hydroxyethyl)amine and phen and bpy are 1,10-phenanthroline and 2,2'-bipyridine, respec制川乌的功效与作用
男孩遗精
tively. The crystal structure of 1 ·2EtOH has been determined by single-crystal X-ray analysis. It crystallizes in the monoclinic system, space group C2/c, a= 24.279(2), b= 20.864(2), c= 17.635(1), g = 121.730(2)°, Z= 8, R 1= 0.064, wR 2= 0.167. The Ni(II) ion in 1 ·2EtOH is coordinated to three nitrogen atoms and one oxygen atom of the ligand L and two nitrogen atoms of phen to form a distorted octahedron. Spectroscopic properties of 1 and 2 are reported.
内容由中国教育图书进出口有限公司引进
