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Synthesis, structural characterization, and properties of two new polyoxovanadates bad on decavanadate [V10O28]6−
期刊名称： Journal of Coordination Chemistry
作者： Wentao Hou,Jiuyu Guo,Zuoxiang Wang,Yan Xu肾阳虚怎么治疗
年份： 2013年
环境整治实施方案
橡皮娃娃期号： 第14期
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关键词： Hydrothermal synthesis;Polyoxovanadates;Organic–inorganic hybrid害怕上当
material;Crystal structure;Hydrogen bond
摘要：Two new decavanadate metal compounds, [Co(pyim)3]2[V10O28]·7H2O (1) and [Ni(pyim)3]2[H2V10O28]·4H2O (2) (pyim=2-(2-pyridyl)-imidazole), have been synthesized under hydrothermal conditions and characterized by elemental analysis, single-crystal X-ray diffraction analys
人教版二年级下册数学教案is, infrared spectra, powder X-ray diffraction analysis, and thermogravimetric analysis. Crystallographic analysis reveals that 1 is constructed from [V10O28]6, metal cation [Co(pyim)3]3+, and water. [V10O28]6 clusters are connected by waters through O–HO hydrogen bonds to form a sheet structure which is further connected by N–HO hydrogen bonds to form a 3-D supermolecular framework. In 2, although [Ni(pyim)3]2+ is similar to [Co(pyim)3]3+ in 1, the MO cluster anion is protonated [H2V10O28]4.
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