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Synthesis, crystal structures and characterization of two Cu(II) complexes with asymmetric sulfonamide
出国护照如何办理
京城驾校Schiff-ba ligands
期刊名称: Journal of Coordination Chemistry欲开头的成语
作者: Shu-Ni Li,Yu-Cheng Jiang消化系统模型
沙白豆腐汤
年份: 2009年
期号: 第16期
关键词: N-tosyl-1, 2-propanediamine, N-tosyl-o-phenyldiamine, Sulfonamide
Schiff ba, Quantum chemical calculation, Fluorescence愉
摘要:Reaction of the N-tosyl-1,2-diaminopropane or N-tosyl-1,2-diaminobenzene with salicylaldehyde forms two new asymmetric sulfonamide Schiff bas, N-[2-(2-hydroxybenzylideneamino)propyl]-4-meth
咨询服务费合同范本ylbenzenesulfonamide
(H2L1) and N-[2-(2-hydroxybenzylideneamino)phenyl]-4-methylbenzenesulfonamide (H2L2). Two new complexes [CuLx(H2O)] (x = 1 for 1, x
= 2 for 2) constructed from H2Lx have been prepared and characterized via X-ray single-crystal diffraction, elemental analysis, FT-IR, UV-Vis, TGA, quantum chemical calculations, and photoluminescence measurements. Weak C–H ··· π, hydrogen bonds, π–π, and Cu ··· O weak interactions lead to 3-D supramolecular architecture, 1, and 1-D double chain, 2.
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