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Synthesis and characterization of 1′,1′′′-
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bis(ethynyl)biferrocenyl derivatives 期刊名称: Journal of Coordination Chemistry
作者: Li-Min Han,Yu-Qiang Hu,Quan-Ling Suo,Mei-Hua Luo,Lin-Hong Weng
微信登陆年份: 2010年
期号: 第4期
关键词: Biferrocene;Cross coupling reaction;Molecular structure;Electron
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摘要:Three alkynylbiferrocenyl derivatives (1–3) were synthesized by cross coupling of 1′,1′′′-diiodobiferrocene with the corresponding alkynyl cuprous species and characterized by elemental analysis, FT-IR, NMR, and MS. The molecular structures of C6H5C≡CFc′Fc′C≡CC6H5 (1), NO2–C6H4C≡CFc′Fc′C≡CC6H4–NO2 (2), and I–Fc′Fc′C≡CC6H4Fc (3) have been identified by X-ray single 绿豆沙怎么做
crystal diffraction. The electrode reaction process of 1–3 were investigated by cyclic voltammetry, square wave voltammetry, and microelectrode chronoamperometry.吉林省的大学
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