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陶瓷材料因其优异的性能被誉为“未来的材料”,在口腔修复领域,陶瓷材料以其极佳的生物相容性、良好的耐磨、耐腐蚀性和类似天然牙的美学性能成为修复材料的首选。自上世纪六十年代人们解决了金瓷匹配问题后,以金属底层冠增强的金属熔附烤瓷牙(PFM)成为口腔临床最为常用的固定修复方式,但金属底层的存在使金属烤瓷牙存在着难以克服的缺点,例如:金属离子的析出有潜在的致敏性,析出的金属离子可导致龈缘灰线影响美观,遮色层的存在阻止了光线透过使人工牙缺乏天然牙活力等。因此能够以高强度陶瓷材料取代底层金属冠,以达到最佳美学效果和生物相容性的全瓷修复已成为近年的研究热点和口腔修复的发展方向,并相继出现了IPS Impress热压铸陶瓷、In-Ceram系列粉浆涂塑渗透铝瓷等全瓷材料,近年又与先进的计算机辅助设计/计算机辅助制作(CAD/CAM)技术相结合研制出可机械加工的In-Ceram多孔铝瓷和Procera All Ceram高铝瓷预成瓷块,大大推进了全瓷修复体在临床的应用。但由于陶瓷材料的位错运动,这种脆性本质限制了陶瓷材料的实际应用,克服其脆性、提高其韧性一直是材料学家们努力要解决的问题。但由于陶瓷材料的化学键大都为离子键和共价键,键结合牢固并有明显的方向性,室温下几乎不能产生滑移或位错运动,这种脆性本质限制了陶瓷材料的实际应用,克服其脆性、提高其韧性一直是材料学家们努力要
解决的问题传统的陶瓷增韧方法有相变增韧、纤维增韧、晶须及颗粒韧化等,其中最为引人注目的材料之一是氧化锆相变增韧陶瓷,由于在应力作用下诱发四方相向单斜相的马氏体相变而使其断裂韧性大大提高,成为室温下韧性最好的陶瓷材料,故有“陶瓷钢”的美誉,而且其粉体还可以作为第二相颗粒填加到其它陶瓷基体中起到相变增韧作用。近年来氧化锆陶瓷优良的力学性能也引起了口腔医学家们的关注,成为引人注目的新型牙科材料。除了传统的增韧方法,近年来纳米科技的发展使新材料、新技术不断涌现,纳米陶瓷被认为是解决陶瓷脆性的战略途径。当前纳米氧化锆及纳米氧化锆复合陶瓷已成为材料学界的研究热点。
关键词:牙科陶瓷;氧化锆;氧化铝;纳米粉体;沉淀法;超声波;正多边形定义纳米复合陶瓷;力学性能
Abstract
Ceramic is praid as“future material”for its unique properties,especially is considered to be the best choice as prosthetics materials becau of its excellent biocompatibility、corr
osion and abrasive resistance、学习机排名nature aesthetic traits.Now the porcelain-fud-to-metal (PFM)restoration has become the most commonly clinical restorative way since the matching problem between ceram and metal material was resolved in the 60s’last century.But the metal substructures exist many shortcomings such as the poor biocompatibility and poor aesthetics caud by the deposition of metal ions,the abnce of nature vigour becau of the poor transparence,et al. To overcome the disadvantages, all-ceram restoration which substitute the ceramic core crown for metal substructure has become the developping trend and rearching focus.But the inherent brittleness and lower strength limit the all-ceram materials’ archers are attemping to overcome the brittleness、enhance its fracture strength and toughness. With the developping of nanotechnology, nano-ceramic was considered to be the statistic way to resolve ceramic’s brittleness. So the key idea in this study was to bring nano-materials into dental material rearch,combine the toughening effect of pha transformation of Zirconia and nano-particles to develop new type of Zirconia nano-ceramic composites,which have better mechanical properties and can meet the demand of prosth
etics material.In addition,we try to u advanced S P Stechnology to develop Zirconia nano-ceramic composites for dental application,and get some benefit results.
Keywords:dentalceramic;zirconia;aluminia;precipitation;ultrasonic;nano-powder;nano-composite ceramic materials;mechanical properties.
目录
摘要形容幸运的成语..........................................................Ⅰ
Abstract......................................................Ⅱ
目录 .........................................................Ⅲ
第一章 绪论 ..................................................1
1.1陶瓷 ..............................................................1
1.2氧化锆 ...............................................................3
1.3识字课教案纳米氧化锆陶瓷 ......................................................8
第二章 纳米氧化锆陶瓷的相变增韧机制及制备 ....................11
2.1氧化锆的相变及特点 ..................................................11
2.2氧化锆的增韧机制 ...................................................12
2.3氧化锆的制备方法 ...................................................14
2.4 纳米氧化锆的主要增韧机理 ........................................... 16
2.5 纳米氧化锆的主要制备方法 .......................................... 18
2.6纳米氧化锆的制备实验 .............................................19
2.7 纳米氧化锆的性能实验 ............................................... 23
第三章 平面磨削过程中温度场数值仿真的有限元分析 ....................... 28
3.1 有限元模型的建立 ...............................................28
3.2 磨削区温度场的求解化生名词解释 ...............................................34
3.3 磨削区温度场的后处理 ...............................................37
3.4磨削参数对磨削区温度场的影响........................................ 39
第四章 纳米氧化锆陶瓷磨削机理及磨削实验 ....................41
4.1 传统磨削理论 .................................................. 41红烧黄豆猪蹄
4.2 纳米氧化锆材料磨削机理 ..............................................43
4.3 纳米氧化锆高效深磨磨削力的试验 ....................................45
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