止血读音Chemical Enhancement vs Molecule–Substrate Geometry in Plasmon-Enhanced Spectroscopy 期刊名称: ACS Photonics
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作者: Raul D. Rodriguez,Carlos J. Villagómez,Amirhassan Khodadadi,Stephan Kupfer,Evgeniya Sheremet
年份: 2021年
关键词: quantum chemistry;phthalocyanines;surface-enhanced Raman梨花头短发
spectroscopy;nanospectroscopy;plasmonics;spectral artifacts;SERS
万忠墓摘要:Light interaction with metal nanostructures expos exciting phenomena such as strong amplification and localization of electromagnetic fields. In surface-enhanced Raman spectroscopy (SERS), the strong signal amplification is attributed to two fundamental mechanisms, electromagnetic and chemical enhancement (EM and CM, respectively). While the EM mechanism is accepted as the main responsible for signal amplification, a long-standing controversy on the CM mechanism's role still 丝的形近字
简短签名prevails. The CM contribution can be evidenced when compared to the nonenhanced (or bulk) Raman signal as a change in intensity ratios, peak shifts, or appearance of new Raman modes. However, it is also possible to induce similar spectral variations by changing the relative orientation between the electric field and molecule or when a high electric 床头柜一般多宽
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