老房子翻新改造Enhanced Photofixation of Dinitrogen to Ammonia over a Biomimetic Metal (Fe,Mo)-Doped
Mesoporous MCM-41 Zeolite Catalyst under
Ambient Conditions
期刊名称: ACS Sustainable Chemistry & Engineering
事业单位年度考核表
作者: Suresh Thangudu,Chien-Hou Wu,Chih-Hao Lee,Kuo Chu Hwang
年份: 2021年
幼儿园师德故事关键词: Michaelis?Menten reaction kinetics;biomimetic;Haber?Bosch送奶奶什么礼物好
百尺竿头什么意思
生日四字祝福语process;solar energy conversion;N2 fixation
穿越时光摘要:Theconversion of dinitrogen to ammonia is a great challenge todayin diver applications related to the fields of energy, environment,and hydrogen storage. Till date, industrial production of ammoniaremains relying on the energy-and capital-intensive Haber–Boschprocess. Owing to the large
N N triple bond energy (226 kcal/mol),N 2 activation remains as an intriguing and challengingtask since years. A biomimetic photochemical approach is believedto be a promising alternative to replace the high-energy-consumingHaber–Bosch process due to its clo remblance to naturalnitrogen fixation process. Herein, we investigate a photo activationand cleavage of dinitrogen on an as-synthesized biomimetic metal (Fe,Mo)-dopedmesoporous MCM-41 zeolite catalyst (FM-MCM 41), which offers a goodammonia formation yield, 644.87 μmol h –1 g –1 ,...
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