Nippon Polyurethane Industry Co., Ltd.
15F Mita NN Bldg. 4-1-23, Shiba, Minato-ku, Tokyo 108-0014 Japan Phone: +81-3-5439-8600 Fax: +81-3-5439-8610
Product name: CORONATE 4403
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name CORONATE 4403
General description Modified polyisocyanate Company Identification Company name Nippon Polyurethane Industry Co., Ltd. Department High Performance Urethane Dept. Address 4-1-23, Shi
ba, Minato-ku, Tokyo Japan Telephone (Emergency telephone) +81-3-5439-8622
( Monday ~ Friday, Japan standard time 9: ~ 6:)
2. HAZARDS IDENTIFICATION
GHS classification of the substance or mixture Physical Hazards
・ Flammable liquids Not classified ・ Flammable solids Not applicable Health Hazards
・ Acute toxicity (oral) Not classified ・ Acute toxicity (skin) Not classified ・ Acute toxicity (inhalation: gas) Not applicable ・ Acute toxicity (inhalation: vapour) Not applicable ・ Acute toxicity (inhalation: dust, mist) Category 4 ・ Skin corrosion/irritation Category 2 ・ Serious eye damages/eye irritation Category 2 ・ Respiratory nsitization Category 1 ・ Skin nsitization Category 1 ・ Germ cell mutagenicity Classification not possible ・ Carcinogenicity Classification not possible ・ Reproductive toxicity Classification not possible ・ Specific target organ toxicity; single exposure Category 3
(Respiratory tract irritation)
・ Specific target organ toxicity; repeated exposure Classification not possible ・ Aspiration hazard Not classified
Nippon Polyurethane Industry Co., Ltd.
15F Mita NN Bldg. 4-1-23, Shiba, Minato-ku, Tokyo 108-0014 Japan Phone: +81-3-5439-8600 Fax: +81-3-5439-8610
Product name: CORONATE 4403
Environmental Hazards
・ Aquatic toxicity (acute) Classification not possible ・ Aquatic toxicity (chronic) Classification not possible
Section is not listed, it can not be excluded from ‘Not applicable’ or ‘Classification not possible’
GHS label elements including precautionary statements
Symbol
：
Signal word ： Danger Hazard statement ：
・ Harmful if inhaled ・ Caus skin irritation
・ Caus rious eye irritation
・ May cau allergy or asthma symptoms or breathing difficulties if inhaled ・ May cau an allergic skin reaction ・ May cau respiratory irritation
Precautionary Statements Prevention
・ Obtain special instructions before u.
・ Do not handle until all precautions have been read and understood. ・ Keep container tightly clod.
(There is a danger of explosion if the carbon dioxide generated when water enters.) ・ Not to treat an allergic reaction to a person.
安全生产宣传栏・ U only outdoors or in a well-ventilated area. ・ Do not breathe dust/ fume/ gas/ mist/ vapour/ spray.
・ Wear protective gloves/ eye protection/ face protection/ protective clothing (Regulatory
Nippon Polyurethane Industry Co., Ltd.
15F Mita NN Bldg. 4-1-23, Shiba, Minato-ku, Tokyo 108-0014 Japan Phone: +81-3-5439-8600 Fax: +81-3-5439-8610
Product name: CORONATE 4403
authorities, manufacturer or supplier specified). Wash thoroughly after handling. ・ If ventilation is not sufficient,wear respiratory protection. (Regulatory authorities, manufacturer or supplier specified.)
・ Contaminated work clothing should not be allowed out of the workplace. Respon
・ In ca of fire: U dry chemical powder, carbon dioxide, foam, large volumes of water spray.
・ If swallowed: Rin mouth with water. Do not induce vomiting. To contact a doctor immediately.
・ If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. To contact a doctor immediately.
・ If in eyes: Rin cautiously with water for veral minutes. Remove contact lens, if prent and easy to do. Continue rinsing. To contact a doctor immediately.
・ If on skin (or hair): Remove/take off immediately all contaminated clothing. Rin skin with water/shower. To contact a doctor immediately. ・ If on skin : Wash with plenty of soap and water.
・ Seek medical advice/attention if you feel unwell or if skin irritation or rash occurs. ・ After handling, wash your hands.
・ If you want to reu contaminated clothing,wash it.
・ Sprayed with a neutralizing agent to neutralize or remove adsorbed sand, earth, sawdust, etc..
・ If expod or concerned :Get medical advice/attention. Storage
・ Store container in cool place/ well-ventilated place. Disposal
・ Dispo of contents/container to waste in accordance with local/ regional/ national/ international regulations (to be specified).
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture Substance
Chemical name
Modified polyisocyanate
Nippon Polyurethane Industry Co., Ltd.
15F Mita NN Bldg. 4-1-23, Shiba, Minato-ku, Tokyo 108-0014 Japan Phone: +81-3-5439-8600 Fax: +81-3-5439-8610
Product name: CORONATE 4403
Contents > 99 %
CAS No. Trade cret 【HAZARDOUS INGREDIENT(s)】
学校的操场作文Chemical name 4,4’-diphenylmethane diisocyanate (4,4’-MDI) Contents 37 % CAS No. 101-68-8
4. FIRST-AID MEASURES
If inhaled
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advic
e/attention immediately. If on skin
Take off immediately contaminated clothing and shoes etc.
By washing with water or lukewarm water flow, the part that touches the product. Wash with soap and water.
If there is a change in the appearance, pain persists, ek medical advice or attention. If on eyes
Rin by clean water for 15 minutes or more, and ek ophthalmologist’s advice/attention. During the eyewash, open the lid with your finger well, wash the eyeand rhe lid with water. If swallowed
Rin mouth well.
Spit it in person voluntarily if possible, to vomit. Seek medical advice/attention immediately.
程门立雪文言文5. FIRE-FIGHTING MEASURES
Suitable extinguishing media :
Dry chemical powder, carbon dioxide, foam, large volume of water spray. Unsuitable extinguishing m
edia: Water jet Specific hazards during fire :
There is a risk of generating a hazard gas in a fire. Specific extinction method :
Wear lf-contained breathing apparatus and protective groves, becau cracked gas and steam are generated in the ca of fire.
Water is drained off to the drum, container, equipment etc. that have not ignited, and it
Nippon Polyurethane Industry Co., Ltd.林叠翠
15F Mita NN Bldg. 4-1-23, Shiba, Minato-ku, Tokyo 108-0014 Japan Phone: +81-3-5439-8600 Fax: +81-3-5439-8610
枣加核桃
Product name: CORONATE 4403
tries to prevent spreading, overheating and explosion of containers.黄连上清片说明书
After the fire is extinguished, neutralize the spilled material with decontaminant. In the meantime, not to enter an outsider. Special protective for fire-fighters :
In the extinction work, wear lf-contained breathing apparatus and protective groves, becau cracked gas and steam are generated.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions :
Wear safety glass, rubber gloves, a gas mask for organic gas. Prohibited for outsiders.
Working from the windward, to evacuate people downwind. Better ventilation of the place spilled. Temporary leak repair parts, stop the leak. Environmental precautions :
Do not flow directly into rivers and wage spill.
Fouling and waste are treated on the basis of related regulations . Methods and materials for containment and cleaning up : (Small spill)
Sprayed with a neutralizing agent to neutralize. Remove adsorbed sand, earth, sawdust, etc.
If wiping rags, waste paper, etc., remove and store in a container with a lid. (Large spill)
As spilled liquid can not spread, enclod sand, earth, sawdust, etc.
Recovered in the liquid container as much as possible. Collection container must not be aled.
开发计划
Which could not be recovered sprayed with a neutralizing agent to neutralize or Removed by the above method. Place spilled, washed thoroughly.
Measures to prevent condary disasters :
Promptly except near sources of ignition and prepare a fire extinguishing agent. Using a safety tool that does not generate a spark.
7. HANDLING AND STORAGE
Handling
The operator should be trained in handling this product.春节放几天假
