MATERIAL SAFETY DATA SHEET
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
· Product identification
Synonyms∕Trade Names: Glycerol
· Product us
Serves as a humectant,solvent and lubricant in personal care products.Ud in medical and pharmaceutical preparations.Solvent for flavors and food
coloring.Manufacture mono-and di-glycerides for u as emulsifiers.Ud in surface coatings and paints.Ud as softener and plasticizer.Softening agent in candies,cakes and chee.Ud in explosives.Manufacture of polyols for flexible foams,etc.
· Company/undertaking identification
Name: Teck Guan (China) Ltd
括苍山天气Address: No.1 Teck Guan Road,Rugao Port Economic Development
Zone,Rugao,Jiangsu Province,China.
悲壮的诗句Post Code: 226532
·Emergency Telephone: +86-513-87585000
2. HAZARDS IDENTIFICATION
European Hazard classification: This product is not classified as dangerous according
to Directive 67/548/EEC.
· Potential Health Effects:
Eye - Concentrated solutions may cau mild transient irritation.
Skin - Unlikely to be irritant. Heated product may cau thermal burns if contacted. Inhalation - Not applicable at ambient temperature. Glycerine mist may be irritative to respiratory tract.
Ingestion - Unlikely to be harmful unless excessive amount.
· Physical/Chemical Hazards: Contact of glycerine with strong oxidizing agents such as Nitric Acid or other strong
acids, Chromium Trioxide, Potassium Chlorate, or Potassium Permanganate may cau an explosion.
· Environmental Hazards: Product is biodegradable
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. Wt/Wt % EC-No.
1, 2, 3-Propanetriol 56-81-5 99 - 100 2002895 Occupational exposure limits, if applicable, are listed in Section 8
LC/LD50 information is listed in Section 11.
4. FIRST AID MEASURES
·
Eye - Immediately flush with copious amounts of water. Get medical attention if irritation persists.
· Skin - Wash thoroughly with plenty of water and soap.
· Inhalation - Remove to fresh air.
· Ingestion - Remove material from mouth. Drink plenty of water. If large amount swallowed or symptoms develop get medical attention.
5. FIRE FIGHTING MEASURES
· Extinguishing media: U water, alcohol resistant foam, CO2 or dry chemical.
· Unsuitable extinguishing media: Not applicable
· Flash Point and method: >390° F (198.9° C) PMCC
· Explosive limits in air: Not applicable
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男生喜欢女生· Auto-ignition temperature: ~752º F (~400º C)
· Sensitivity to mechanical impact/static discharge: Not available
· Special Protective Equipment: Wear lf-contained breathing apparatus and full
protective clothing.
· Other Fire Fighting Considerations: Contact of glycerine with strong oxidizing agents such as Nitric Acid or other strong acids, Chromium Trioxide, Potassium Chlorate, or Potassium Permanganate may cau an explosion.
· Exposure hazards: During burning poisonous acrolein may be formed.
6. ACCIDENTAL RELEASE MEASURES
· Personal Precautions: Wear respirator, suitable gloves and eye/face protection.
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· Environmental Precautions: Minimize contamination of drains, surface and ground
waters.
· Procedures for Spill/Leak Clean-up: Transfer product to suitably labeled containers for disposal at an approved site. Absorb liquid spillage onto inert material (e.g. sand). Residues and small spillages may be washed away with water and detergent.
Refer to Section 8 for additional personal protection information.
Refer to Section 13 for disposal considerations.
7. HANDLING AND STORAGE
· Handling: No special precautions required, but avoid eye and skin contact as part of normal industrial hygiene.Prevent formation of mist. Eye and skin contact
should be avoided if handling at elevated temperatures.
· Storage: Store in clean tight containers to prevent moisture pickup from air. Can be stored in aluminum, stainless steel, fiberglass or resin lined steel vesls. · Other Recommendations: Avoid contact with strong oxidizing agents such as Nitric
Acid or other strong acids,Chromium Trioxide, Potassium
Chlorate, or Potassium Permanganate.
· Specific u(s): Follow bulk handling and storage procedures as noted above.
Refer to Section 6 for clean-up of spillages.
Refer to Section 13 for disposal considerations.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
· General Precautions: Good industrial hygiene should be followed.
Avoid breathing mist.
· Exposure Limit Values - glycerine: 10 mg/m3
· Exposure Controls:
Engineering Controls: Ventilation: Local exhaust - preferred
Mechanical (general) acceptable
Provide ventilation to meet exposure limits.
Personal Protective Equipment:
Eye - None required, although eye protection is recommended as part of good industrial hygiene.
Skin - Protective gloves: None required with normal u.
Inhalation - An appropriate NIOSH/MSHA approved respirator should be ud if a mist or vapor is generated.A NIOSH/MSHA approved lf-contained
breathing apparatus or air-supplied respirator is recommended if the
concentration exceeds the capacity of cartridge respirator. WARNING: Air
purifying respirators do not protect workers in oxygen-deficient atmospheres. Other Controls: None required.
9. PHYSICAL AND CHEMICAL PROPERTIES
· General Information:
Physical State: Liquid
Appearance: Water white, clear
Odor: Bland odor; sweet taste
Odor Threshold: Not available
· Important health, safety and environmental information:
pH: Neutral
Boiling point/Boiling range: > 554° F (290° C) @ 760 mm Hg (101.3kPa)
Flash Point & Method: >390 °F (198.9 °C) PMCC
Flammability (solid, gas): Not available
Explosive properties: Not to be expected
Oxidising properties: Not to be expected
Vapor pressure: 0.0025 mmHg @ 122° F (50° C)
Relative density: 1.26 @ 68° F (20° C)
Freezing point: Not available
Melting Point: ~64.4º F (~18º C) (solidifies at a much lower temperature) Solubility:Water solubility: Complete @ 72º F (22.2 ° C)
Fat solubility (solvent-oil to be specified): Miscible with ethanol Slightly
soluble in acetone Insoluble in ether and in chloroform
Partition coefficient (Log Pow) (calculated): -1.76
Viscosity: 1410 mPa.s at (68° F) 20º C
Vapor density: Not available
Evaporation Rate (nBuOAc=1): Not available
Explosive Limits: Not applicable
Auto ignition temperature: ~739.4º F (393º C)
Coefficient of water/oil distribution: Not available
10. STABILITY AND REACTIVITY
· Stability: Stable under normal operational procedures.
· Conditions to Avoid: None identified.
· Materials to Avoid: Contact of glycerine with strong oxidizing agents such as Nitric Acid or other strong acids, Chromium Trioxide, Potassium Chlorate, or Potassium Permanganate may cau an explosion.
· Hazardous Decomposition Products: Does not decompo up to 204° C (400° F) Thermal decomposition may relea acrolein.
· Hazardous Polymerization: No hazardous polymerization reactions.
11. TOXICOLOGICAL INFORMATION
·IRRITATION DATA
Skin, rabbit Not irritating
Eye, rabbit Not irritating
·TOXICITY DATA
LD50 oral, rat >2 g/kg
12. ECOLOGICAL INFORMATION
· Ecotoxicity:
Carassius auratus (Goldfish) 24h LC50 >5,000 mg/L
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Leuciscus idus (Golden Orfe) 48h LC0 >250 mg/L
Oncorhynchus mykiss (Rainbow trout) 96h LC100 = 51,000 – 57,000 mg/L Daphnia magna 24h EC50 >10,000 mg/L
Daphnia magna 24h EC0 >500 mg/L
Microorganisms
Chlimonas paramaecium 48h NOEC >10,000 mg/L
Entosiphon sulcatum 72h NOEC 3200 mg/
Pudomonas putida 16h NOEC >10,000 mg/L
Uronema parduzci 20h NOEC >10,000 mg/L图书漂流
Algae
Microcystis aeruginosa 8d NOEC 2900 mg/L
Scenedesmus quadricauda 8d EC0 >10,000 mg/L
· Mobility:
Low potential for sorption to soil. Glycerol will partition primarily to water.
· Persistence and degradability:
Readily biodegradable (OECD 301)
· Bioaccumulative potential:
BCF: 3.162 (calculated)
13. DISPOSAL CONSIDERATIONS
Product Disposal: Waste incineration with the approval of the responsible local
authority.
14. TRANSPORT INFORMATION
Not restricted for transport. Not a hazardous material according to RID/ADR, GGVS/GGVE, ADNR, IMDG, ICAO-TI/IATA-DGR。
15. ADDITIONAL REGULATORY INFORMATION
Classification and labelling according to GefStoffv:
Symbols of danger:Not subject of the identification regulations.
R-phras :Not applicable.
S-phras:Not applicable.白夜逃亡
National prescriptions:WGK= 0. (classification by the German commission).
16. OTHER INFORMATION
This information is bad on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requireme
nts and is not intended to guarantee any particulars properties.
