MATERIAL SAFETY DATA SHEET
关于兔子的古诗SECTION 1 - IDENTIFICATION OF THE SUBSTANCE AND COMPANY
自启动Company Address: The National Company For Agrochemicals & Investment
473 El_horreya St., Bolkly Alexandria-Egypt
Tel.: (203) 5440640/1 Fax.: (203) 5411150
Product Name: Carbendazim
CAS RN: 10605-21-7
CUS (Customs union and statistics number):27248
CN-Code (Combined Nomenclature code):2933 99 90
Chemical Name: Methylbenzimidazol-2-ylcarbamate
Chemical family: Benzimidazole
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Component Percentage
Carbendazim 98% SECTION 3 - IDENTIFICATION OF HAZARDS
Emergency Overview:
- Carbendazim is very rapidly absorbed and eliminated from the body.
- Carbendazim is NOT a cholinestera inhibitor.
- Harmful if absorbed through skin or inhaled.
- Avoid breathing product vapors or spray mist.
- Avoid contact with eyes, skin or clothing.
- Keep out of reach of children.
Symptoms of over exposure are headache, naua, vomiting, cramps, weakness, blurred vision, pin
point pupils, tightness in chest, labored breathing, nervousness, sweating, watering of eyes, drooling, muscle spasms and coma.
Potential Health Hazards:
Eye- No irritant to eye.
Skin- No irritant to skin. The dermal toxicity of this product is low. However, skin contact should be avoided. This product is not a skin nsitir.
Inhalation- May be a slight respiratory irritant.
Ingestation- The acute toxicity of this product is low, but it may be harmful if a large amount is swallowed.
Potential Physical Hazards:Oxides of carbon and nitrogen may be given off when
expod to extreme heat or fire.
SECTION 4- FIRST AID MEASURES
Inhalation: If inhaled, remove to fresh air and keep at rest. Obtain medical advice if at all worried.
Skin contact: Carefully remove contaminated clothing. Wash affected areas with soap and water. Seek medical aid if at all worried.
Eye contact: Rin eyes immediately with clean water for at least 15 minutes and obtain medical aid.
Ingestion: Wash out mouth with water. Do not induce vomiting. Keep patient at rest and ek medical advice as above.
Fi r st Aid
Facilities: Provide washing facilities in the workplace including eyewash.
Symptoms: The following symptoms may occur: Local – No skin and eye irritation.
Systemic – none documented over many years’ experience.
Medical attention:
For local contamination treatment should be for symptoms after decontamination. In ca of skin or
eye contamination, treat as documented under “First Aid”.
If a large amount of this product is ingested the following measures should be considered: Induction of vomiting if the patient is fully conscious and it is less than 30 min since ingestion.
Monitor blood count, Gastric lavage, Charcoal administration, Anticonvulsant therapy is not appropriate.
There is no specific antidote for poisoning with carbendazim.
Recovery is expected to be spontaneous.乐家杏仁糖
Carbendazim is very rapidly absorbed and eliminated from the body.
Carbendazim is NOT a cholinestera inhibitor.
SECTION 5 - FIRE FIGHTING MEASURES
Extinguishing media: Water spray, foam, dry agent, carbon dioxide
Hazards from combustion products:
Oxides of carbon and nitrogen may be given off when expod to extreme heat or fire. Precautions for fire fighters:
Firefighters should wear full protective gear, including lf-contained breathing apparatus (AS/NZS 1715/1716). If possible and without risk, remove intact containers from exposure to fire. Otherwi, spray unopened containers with water to keep cool. Contain fire-fighting water by bunding area with sand or earth to prevent it entering any bodies of water. Dispo of fire control water or other extinguishing agent and spillage later.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Avoid contact with the spilled material or contaminated surfaces. When dealing with spills do not eat, drink or smoke and wear personal protective clothing and equipment as described in the PERSONAL PROTECTION ction below. Prevent spilled material from entering drains or watercours. Contain spill and absorb with earth, sand, clay, or other absorbent material. Collect and store in properly labelled, aled drums for safe disposal. Deal with all spillages immediately. If contamination of drains, streams, watercours, etc. is unavoidable, warn the local water authority. Neutralizing chemicals are not required.
SECTION 7 - HANDLING AND STORAGE
Handling: Keep out of reach of children. Avoid contact with the eyes and skin. Storage: Store in the clod, original container in a dry, cool, well-ventilated area.
Do not store for prolonged periods in direct sunlight. Store in a locked room or
place away from children, animals, food, animal feed, ed and fertilizers. Store
below 40°C. Protect from frost.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Exposure standards:
No exposure standard has been assigned by the National Occupational Health and Safety Commission for the product or its ingredients. The exposure standard for carbendazim t is 0.5 mg/m³.
Engineering controls:
Control process conditions to avoid contact. U local exhaust ventilation during manufacture. U in a well-ventilated area only.
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Personal Protective Equipment:
爱玖玖To avoid eye and skin contact, wearing the following personal protective clothing and equipment is recommended:
Eyes: Safety goggles or face shield
Clothing: Cotton overalls buttoned to the neck and wrist and a washable hat
Gloves: Elbow length PVC gloves
Respiratory: Respiratory protection is not normally required. If airborne concentrations are likely to exceed the exposure standard above, an AS/NZS 1715/1716 approved respirator should be worn.
Other: After u and before eating, drinking or smoking, wash hands, arms and face thoroughly with soap and water. After each day’s u wash gloves, goggles or face shield and contaminated clothing.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL DESCRIPTION: Crystalline powder.
ODOR: Practically odorless
MOLECULAR WEIGHT: 191.2铁路院校
MOLECULAR FORMULA: C9H9N3O2
BOILING POINT: Not applicable
MELTING POINT: 302-307°C (decomp.).
SPECIFIC GRAVITY: 1.45 (20°C)
VAPOR PRESSURE: 0.09 mPa (20°C)
FLAMMABLE: Not flammable
SECTION 10 - STABILITY AND REACTIVITY
微信群名字搞笑逗比
CHEMICAL STABILITY: Decompos at m.p.; stable for at least 2 y below 50o C.
Stable after 7 d at 20 000 lux. Slowly decompod in alkaline solution (22 o C); DT50 >350 d (pH 5 and pH 7), 124 d (pH 9). Stable in acids, forming water-soluble salts CONDITIONS TO AVOID: Extreme heat and fire.
INCOMPATIBILITY WITH OTHER MATERIALS: incompatible with alkaline materials. HAZARDOUS POLYMERIZATION: Non-known.
SECTION 11 - TOXICOLOGICAL INFORMATION
ACUTE TOXICITY:
Oral LD50 (rat) - >15000 mg/Kg
Dermal LD50 (rabbit) - >10000 mg/Kg
Inhalation LC50 (rat) - Not effect with suspension (10 g/l water).
Eye Irritation (rabbit) - Non-irritating
Skin Irritation (rabbit) - Non-irritating
Sensitization (guinea pig) - Not-nsitizer
MUTAGENIC DATA: Carbendazim is classified as a Category 3 Mutagen, i.e. insufficient evidence to classify as a mutagen. Studies indicate that reproductive and teratogenic effects in humans are unlikely at expected exposure levels.
SECTION 12 - ECOLOGICAL INFORMATION
ENVIRONMENTAL SUMMARY: DO NOT contaminate streams, rivers or waterways with the chemical or ud containers. Toxic to aquatic organisms. Low hazard to birds. Do not apply directly to water, or to areas where surface water is prent. Drift and runoff from treated areas may be hazardous to aquatic organisms in adjacent aquatic sites.
FISH TOXICITY: 96 hour LC50, Rainbow trout – 0.83 mg/l
AVIAN TOXICITY: Oral LD50, quail - 5826-15 595 mg/kg.
BEE TOXICITY: LD50 (contact) >50 µg/bee.
腰带蝴蝶结的系法图解Environmental fate, persistence and degradation:
Carbendazim decompos in the environment DT50 6 to 12 months on bare soil, 3 to 6 months on turf and 2 and 25 months in water under aerobic and anaerobic conditions respectively.
