Second-Order Jahn–Teller (SOJT) Structural Distortions in Multiply Bonded Higher Main Group
Compounds
Kairo期刊名称： Organometallics
苜蓿芽作者： Wedler Henry B.,Wendelboe Paul,Power Philip P.
年份： 2018年自洁
丢掉幻想准备斗争摘要：Thegeometrical deviations from planar to folded or from linearto bent structures obrved in multiply bonded heavy main group elementanalogues of ethylene and acetylene are treated from a cond-orderJahn–Teller (SOJT) perspective. The structural distortionscan be regarded as a conquence of a mixing of the filled highestoccupied molecular orbital (HOMO) and an unoccupied orbital (LUMO+1).This mixing stabilizes the HOMO and destabilizes the unoccupied LUMO+1orbital and produces nonbonding electron density, which caus thegeometrical distortion through interelectronic repulsion. This occursmore readily in the heavier species becau of their generally wea在操场上
现代诗自创kerbonds, which permit a clor approach and hence greater interactionof the molecular levels. Predicting which geometrical distortion enablesthe HOMO/LUMO+1 mixing 宿舍安全
内容由中国教育图书进出口有限公司引进
重男轻女打一地名
