格调沙发国税面试SYNTHESIS, STRUCTURE AND CHARACTERIZATION OF THE CUBANE-LIKE CLUSTER
房山景点{WAG3S3[S2P(OCH2CH3)2]}(O)(PH3P)3 AND THE DOUBLE CUBANE-LIKE CLUSTER值得一读的好书
{W2AG6S6[SC(CH3)3]2}(O)2(PH3P)4期刊名称： Journal of Coordination Chemistry
作者： S. W. Du,X. T. Wu
年份： 1993年城市防洪
解析包错误期号： 第2期
关键词： Cubanes;tungsten;silver;thio ligands;X-ray structures
摘要：Two novel W-Ag-S cubane-like and double cubane-like heterometallic clusters {WAg3S3[S2P(OCH2CH3)2]}(O)(Ph3P)3 I and {W2Ag6S6[SC(CH3)3]2}
(O)2(Ph3P)4 II were obtained from the reaction of the butterfly compound
{WAg2S3}(O)(Ph3P)3 with AgS2P(OCH2CH3)2 and AgSC(CH3)3, respectively. Cluster I
is triclinic, space group PI with cell parameters a = 14.275(3), b = 19.96(1), c =
11.746(4) , ± = 98.58(4), = 107.68(2), = 87.88(3)°, U = 3153(2) 3, Z = 2, Cluster II is also triclinic, space group PI, with cell parameters a = 13.529(6), b = 15.825(9), c =
做什么小生意赚钱11.348(5) , ± = 102.11(4), = 102.53(4), = 66.99(4)°, U = 2162(2) 3, Z = 1. Triply bridging modes of the S2P(OCH2CH3)2 and SC(CH3)3 ligands were found. The bidentate
S2P(OCH2CH3)2 ligand completes the cubane-like core of cluster I and the monodentate SC(CH3)3 links two
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