Safety Data Sheet according to GB/T 16483-2008
Page 1 of 7 . 242 Threadlocker 250ML EN/CH/JP
SDS No. : 150233
V001.8
Revision: 21.02.2013
Printing Date: 05.03.2014
1. Identification of the substance/preparation and of the company/undertaking
Product name: 242 Threadlocker 250ML EN/CH/JP
Intended u: Anaerobic
Company name:
Henkel (China) Investment Co., Ltd.
No.928 Zhangheng Rd.
P.R.China
201203 Pudong,
Shanghai,
China
Phone: +86-21-2891 8000
Fax-no.: +86-21-2891 5137
Revision date: 21.02.2013
Emergency information: Emergency telephone: +86 532 8388 9090 (24h).
2. Hazards identification
asmble
Classification of the substance or mixture according to GB 13690-2009 (General rule for classification and hazard
communication of chemicals):
Hazard Class Hazard Category Route of Exposure Target Organ(s)
Eye Damage/Irritation Category 2A Eye contact
Specific target organ toxicity -
上海美发学校Category 3 Lungs
single exposure
Label elements according to GB 15258-2009 (General rules for preparation of precautionary label for chemicals):
Pictogram:
Signal word: Warning
Hazard statement: H319Caus rious eye irritation.
H335May cau respiratory irritation.
Precautionary statement (Prevention): P261Avoid breathing dust/fume/gas/mist/vapors/spray.
P271U only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement (Respon): P305+P351+P338IF IN EYES: Rin cautiously with water for veral minutes. Remove contact lens, if prent and easy to do. Continue rinsing.
P337+P313If eye irritation persists: Get medical advice/attention.眼线笔的画法
P304+P340IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
Precautionary statement (Storage): P403+P233Store in a well-ventilated place. Keep container tightly clod. P405Store locked up.
Precautionary statement
(Disposal):
P501Dispo of contents/container according to SDS ction 13.
3. Composition / information on ingredients
General description:Anaerobic Sealant
Declaration of the ingredients according to GB 13690-2009:
Hazard component CAS-No. Concentration range GHS Classification
Cumene hydroperoxide 80-15-9 1- 10% Acute
toxicity4; Dermal
H312
Specific target organ toxicity - repeated exposure2
H373
Acute toxicity3; Inhalation
H331
Acute toxicity4; Oral
H302
Organic peroxides E
H242
Chronic hazards to the aquatic environment2
H411奥巴马发脾气
Skin corrosion1B
H314
Cumene 98-82-8 0,1- 1% Flammable
liquids3
H226
Aspiration hazard1
H304
Specific target organ toxicity - single exposure3
H335
Chronic hazards to the aquatic environment2
H411
Only hazardous ingredients for which a classification according to GB 13690-2009 is already available are displayed in this table. For full text of the Hazard statements e ction 16 “Other information”.
4. First aid measures
Skin contact: Wash skin with water
In ca of adver health effects ek medical advice.
Eye contact: Flush eyes with plenty of water for at least 5 minutes. If irritation persists ek medical
attention.
Inhalation: Should not be a problem as product is of low volatility. However, if feeling unwell
remove patient to fresh air.
Ingestion: Rin out mouth, drink 1-2 glass of water, do not induce vomiting.
In ca of adver health effects ek medical advice.
5. Fire fighting measures
Hazardous combustion products: Oxides of carbon, oxides of nitrogen, irritating organic vapors.
Extinguishing media: Foam, extinguishing powder, carbon dioxide.
Fire-fighting method: In ca of fire u foam or powder extinguisher.
Notice and measures for firing
fighting:
None
6. Accidental relea measures
Emergency measures: Ensure adequate ventilation.
Clean-up methods: For small spills wipe up with paper towel and place in container for disposal.
For large spills absorb onto inert absorbent material and place in aled container for
disposal.
7. Handling and storage
Notice for handling: U only in well-ventilated areas.
Gloves and safety glass should be worn
Prolonged or repeated skin contact should be avoided to minimi any risk of nsitisation.
Notice for storage: Store in original containers at 8-21°C (46.4-69.8°F) and do not return residual materials to
containers as contamination may reduce the shelf life of the bulk product.
Temp. limits storage/ transportation:
Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly clod until ready for u.
8. Exposure controls / personal protection
Hazardous components GBZ 2.1-2007 ACGIH NIOSH OSHA Cumene hydroperoxide none none none Cumene none50 ppm TWA none
Engineering controls: No specific ventilation requirements noted, but forced ventilation may still be required if
concentrations exceed occupational exposure limits.
Respiratory protection: U only in well-ventilated areas.
Eye protection: Wear protective glass.
Body protection: Wear suitable protective clothing.
Hand protection: In circumstances where there is a potential for prolonged or repeated skin contact, the u
of polyvinyl chloride or nitrile rubber gauntlets or equivalent solvent resistant gloves is
recommended.
Pictograms for recommended
PPE:
9. Physical and chemical properties
Physical state: liquid Appearance: blue
liquid
pH: Not applicable Melting point: Not available.
Boiling point: > 149 °C (> 300.2 °F) Density: 1,1 g/cm3
Flash point: > 93,3 °C (> 199.94 °F) Ignition temperature: Not available.
Solubility: Slight (Solvent: Water)Viscosity: 800 - 1.600 mPa.s
10. Stability and reactivity
Stability: Stable
Conditions to avoid: Stable under normal conditions of storage and u. Incompatible products: Strong oxidizing agents.
Free radical initiators.
Strong reducing agents.
Alkalis.
Oxygen scavengers.
Other polymerization initiators.
Copper.
Iron.
Zinc.
Aluminum.
Rust.
Decomposition products: Oxides of carbon.
Oxides of sulfur.
Oxides of nitrogen.
Irritating organic vapours.
Hazardous polymerization: Will not occur.
11. Toxicological information General toxicological information:
No experimental toxicological data on the preparation as such is available.
Oral toxicity:
This material is considered to have low toxicity if swallowed.
May cau irritation to the digestive tract.
Other remarks:
Not available.
Acute toxicity:
Hazardous components CAS-No. Value
type
Value Route of
application
Exposure
time
Species Method
Cumene hydroperoxide 80-15-9 LD50
LC50
LD50
550 mg/kg
220 ppm
500 mg/kg
oral
inhalation
dermal
4 h
rat
rat
rat
Skin corrosion/irritation:
Hazardous components CAS-No. Result Exposure
time
Species Method
Cumene hydroperoxide 80-15-9 corrosive
rabbit
Germ cell mutagenicity:
Hazardous components CAS-No. Result Type of study /
Route of
administration
benedictionMetabolic
activation /
Exposure time
Species Method
Cumene hydroperoxide 80-15-9 positive bacterial rever
mutation assay (e.g
Ames test)
without OECD
Guideline
471
(Bacterial Rever Mutation
Assay)
Cumene hydroperoxide
80-15-9
negative dermal mou
12. Ecological information General ecological information:
Do not empty into drains / surface water / ground water.
Ecotoxicity:
和陌生人聊天
No data available.
Persistence and degradability:
Ultimate biodegradation:
Not available.
Bioaccumulative potential:
No data available.
Other adver effects:
Not available.
Toxicity:
Hazardous components大致的英文
CAS-No. Value
type
Value Acute
Toxicity
Study
Exposure
time
Species Method
Cumene hydroperoxide
80-15-9 LC503,9 mg/l Fish96 h Oncorhynchus mykiss OECD Guideline
203 (Fish, Acute
Toxicity Test)
Cumene hydroperoxide
80-15-9 EC5018 mg/l Daphnia48 h Daphnia magna OECD Guideline
202 (Daphnia sp.
Acute
Immobilisation
Test)巴黎出动7000警察
泰晤士报世界大学排名
Cumene hydroperoxide
80-15-9 ErC503,1 mg/l Algae72 h Pudokirchnerella subcapitata OECD Guideline
201 (Alga, Growth
Inhibition Test)
Cumene
98-82-8 LC504,8 mg/l Fish96 h Oncorhynchus mykiss OECD Guideline
203 (Fish, Acute
Toxicity Test)
Cumene
98-82-8 EC50 4 mg/l Daphnia48 h Daphnia magna OECD Guideline
202 (Daphnia sp.
Acute
Immobilisation
Test)
Cumene
98-82-8 EC502,6 mg/l Algae72 h Selenastrum capricornutum
(new name: Pudokirchnerella
subcapitata)pokey
OECD Guideline
201 (Alga, Growth
Inhibition Test)
Persistence and degradability:
Hazardous components
CAS-No. Result Route
of
application
Degradability Method
Cumene hydroperoxide
80-15-9 18 % OECD Guideline 301 E (Ready
biodegradability: Modified OECD
Screening Test)
Cumene
98-82-8 aerobic
86
%
Bioaccumulative potential / Mobility in soil:
Hazardous components
CAS-No.LogKow Bioconcentration
factor (BCF)
Exposure
time
Species Temperature Method
Cumene hydroperoxide
80-15-9 9,1 calculation OECD Guideline 305
(Bioconcentration: Flow-
through Fish Test)
Cumene hydroperoxide
80-15-9
2,16
Cumene
98-82-8 35,5 Carassius auratus OECD Guideline 305
(Bioconcentration: Flow-
through Fish Test)
Cumene
98-82-8 3,55 23
°C OECD Guideline 107
(Partition Coefficient (n-
octanol / water), Shake
Flask Method)
13. Disposal considerations
Product disposal: If the waste is classified as hazardous waste according to GB 5085.7-2007 (Identification
standards for hazardous wastes,General Specifications).Dispo of as hazardous waste in
compliance with "Regulation on the Safety Management of Hazardous Chemicals","Law
of thePeople's Republic of China on the prevention and control of Environmental
Pollution by Solid Waste", "National Catalogue of Hazardous Waste".
Disposal of uncleaned packages: After u, tubes, cartons and bottles containing residual product should be dispod of as
chemically contaminated waste in an authorid legal land fill site or incinerated.
Disposal must be made according to official regulations.
14. Transport information
General information:
Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR.
Notice For Transportation: Transport according to local and national regulations. Ensure
containers will not leak, collap, or being damaged when transported.
DO NOT transport with incompatible materials. Transportation vehicle
should be equipped with right fire-fighting equipment in ca of
emergency. Avoid solarization, drenched and high temperature when
transported.
15. Regulations - classification and identification
The following laws and regulations lay down provisions in terms of chemicals safety u, storage, transportation, loading/ unloading, classification as well as symbol.
“Law of the People's Republic of China on Work Safety” (Adopted by the 28th meeting of 9th NPC standing committee on 29th June 2002).
"Law of the People's Republic of China on the Prevention and Treatment of Occupational Dias" (Adopted by the 24th meeting of 11th NPC standing committee on 31st December 2011)
“Law of the People's Republic of China on environmental protection” (Adopted by 11st meeting of 7th NPC standing committee on 26th December 1989).
“Regulation on the Safety Management of Hazardous Chemicals” (Adopted by 144th State Council executive meeting on 16th February 2011).
“Regulations on Licen to Work Safety” (Adopted by 34th State Council executive meeting on 7th January 2004).
China Inventory of Existing Chemicals:All components are listed or are exempt from Inventory of Existing Chemical Substances in China.
16. Other information
Issue date: 05.03.2014
Issue department: Dayong Tian, Product Safety & Regulatory Affairs Specialist for Greater China
