SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Version 4.1 Revision Date 16.01.2012
Print Date 24.07.2014
GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product identifiers
Product name : Bromocyclopropane
Product Number : C117307
Brand : Aldrich
CAS-No. : 4333-56-6supreme怎么读
1.2 Relevant identified us of the substance or mixture and us advid against
Identified us : Laboratory chemicals, Manufacture of substances
1.3 Details of the supplier of the safety data sheet
Company : Sigma-Aldrich (Shanghai) Trading Co.,Ltd
害怕的英文41F K. Wah Centrre
1010 Huai Hai Zhong Road
200031 SHANGHAI
CHINA
Telephone : +86 21-61415566
Fax : +86 21-61415567
E-mail address :
1.4 Emergency telephone number
Emergency Phone # : +8621-61415560
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Flammable liquids (Category 2)
Skin irritation (Category 2)
Eye irritation (Category 2)
Specific target organ toxicity - single exposure (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Highly flammable.Irritating to eyes, respiratory system and skin.
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Danger
Hazard statement(s)
H225 Highly flammable liquid and vapour.
H315 Caus skin irritation.
H319 Caus rious eye irritation.
H335 May cau respiratory irritation.
Precautionary statement(s)
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P305 + P351 + P338 IF IN EYES: Rin cautiously with water for veral minutes. Remove
contact lens, if prent and easy to do. Continue rinsing. Supplemental Hazard Statements none
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
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R-phra(s)
R11
Highly flammable. R36/37/38 Irritating to eyes, respiratory system and skin. S-phra(s)
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Keep away from sources of ignition - No smoking. S26
In ca of contact with eyes, rin immediately with plenty of water and ek medical advice. S36 Wear suitable protective clothing.
2.3
Other hazards Lachrymator.
3.
COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances
Synonyms
: Cyclopropyl bromide Formula
: C 3H 5Br Molecular Weight : 120,98 g/mol
4.
FIRST AID MEASURES 4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In ca of skin contact
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Wash off with soap and plenty of water. Consult a physician.
In ca of eye contact
Rin thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rin mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
Cough, Shortness of breath, Headache, Naua, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
4.3
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Indication of any immediate medical attention and special treatment needed
no data available
5. FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media
For small (incipient) fires, u media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. U very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen bromide gas
5.3 Advice for firefighters
Wear lf contained breathing apparatus for fire fighting if necessary.
5.4 Further information
U water spray to cool unopened containers.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
U personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (e ction 13).
6.4 Reference to other ctions
For disposal e ction 13.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.
英语六级成绩查询忘记准考证号7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly clod in a dry and well-ventilated place. Containers whic
h are opened must be carefully realed and kept upright to prevent leakage.
Recommended storage temperature: 2 - 8 °C
7.3 Specific end us
no data available
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glass U equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to u. U proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispo of
contaminated gloves after u in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The lected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, Flame retardant antistatic protective clothing, The type of protective
equipment must be lected according to the concentration and amount of the dangerous
substance at the specific workplace.
Respiratory protection
Where risk asssment shows air-purifying respirators are appropriate u a full-face respirator
with multi-purpo combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, u a full-face supplied air
respirator. U respirators and components tested and approved under appropriate government
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standards such as NIOSH (US) or CEN (EU).
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
a) Appearance Form: clear, liquid
Colour: light yellow
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
no data available
e) Melting point/freezing
point
69 °C - lit.
f) Initial boiling point and
boiling range
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g) Flash point -6 °C - clod cup
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower
no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density 1,51 g/cm3 at 25 °C
n) Water solubility no data available
no data available
o) Partition coefficient: n-
octanol/water
no data available
p) Autoignition
temperature
q) Decomposition
no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
9.2 Other safety information
no data available
10. STABILITY AND REACTIVITY
10.1 Reactivity
no data available
10.2Chemical stability
人山人海英文no data available
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Strong oxidizing agents, Strong bas
10.6 Hazardous decomposition products
Other decomposition products - no data available
11. TOXICOLOGICAL INFORMATION
11.1Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin nsitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product prent at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
Inhalation - May cau respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation May be harmful if inhaled. Caus respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin May be harmful if absorbed through skin. Caus skin irritation.
Eyes Caus rious eye irritation.
Signs and Symptoms of Exposure
Cough, Shortness of breath, Headache, Naua, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
