The Effect of Gibbs Adsorption on Marangoni Instability in Penetration Mass Transfer 期刊名称： AIChE Journal
作者： P. L. T. Brian,J. R. Ross
年份： 1972年
期号： 第3期
关键词： Theoretical or Mathematical/ convection; mass transfer/ Gibbs
adsorption; Marangoni instability; penetration mass transfer; Marangoni
convection; surface convection; stabilization; mass transfer penetration depth;
gas liquid mass transfer/ A4725Q Convection and heat transfer
摘要：A theoretical analysis of Marangoni convection in gas-liquid mass transfer shows the stabilizing effect of surface convection in the Gibbs adsorption layer. Results are obtained for various ratios of liqu
id layer thickness to mass transfer penetration depth. For deep liquid layers, complete stabilization results when the inventory in the Gibbs layer equals the solute deficiency in the liquid pha boundary layer, irrespective of the shape of the unperturbed concentration profile. This new theory agrees much better with experimental results than did previous theories. For example, for triethylamine desorption from water, the discrepancy is reduced from a factor of 8,000 to a factor of 8. Speculations are offered concerning this residual discrepancy.
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