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B-Alkyl sp3-sp2 Suzuki-Miyaura Couplings under Mild Aqueous Micellar Conditions.
期刊名称： Organic Letters
aga作者： Nicholas R. Lee,Roscoe T. H. Linstadt,Danielle J. Gloisten,Fabrice
lfreflection
groddGallou,Bruce H. Lipshutz
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作者机构： ‡ACatechol, Inc., Santa Barbara, California93103, United
States,§Novartis Pharma AG, CH-4057Bal, Switzerland
年份： 2018年
期号： 第10期
blowaway摘要：U of B-sp3-alkyl reagents for Suzuki–Miyaura couplings under aqueous micellar catalysis conditions is reported. Studies as to substrate scope, u in a four-step one-pot quence, and reaction medium recycling exemplify the synthetic utility of this technology. OBBD (B-alkyl-9-oxa-10-bor
3s lady
abicyclo[3.3.2]decane) derivatives are easily made and utilized for couplings under mild conditions. Comparisons were also made between OBBD and 9-BBN (B-alkyl-9-宝宝英语早教
eurythmics
borabicyclo[3.3.1]nonane) derivatives as reaction partners.variation
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