bluegill

SPIRAXDELTA-RED

ChemwatchMaterialSafetyDataSheet(REVIEW)

IssueDate:22-Oct-2002CHEMWATCH8041-81

9317TCCD2006/2Page1of6

Section1-CHEMICALPRODUCTANDCOMPANYIDENTIFICATION

PRODUCTNAME

SPIRAXDELTA-RED

SYNONYMS

biocide,"DeltaRed"

PRODUCTUSE

BiocideMaterialismixedandudinaccordancewith

manufacturersdirections.

SUPPLIER

Company:SpiraxSarcoPtyLtd

Address:

72MicaSt

CarolePark

QLD,4300

AUS

Telephone:+61738794944

Telephone:(JONTUBBY)

Fax:

HAZARDRATINGS

Flammability

Toxicity

BodyContact

Reactivity

Chronic

SCALE:Min/Nil=0Low=1Moderate=2High=3Extreme=4

Section2-HAZARDSIDENTIFICATION

STATEMENTOFHAZARDOUSNATURE

ingtothe

CriteriaofNOHSC,andtheADGCode.

POISONSSCHEDULE

None

RISKSAFETY

reathegas/fumes/vapour/spray.

Mayproducediscomfortoftheeyes*.Avoidcontactwithskin.

Possibleskinnsitir*.Weareye/faceprotection.

*(limitedevidence).Tocleanthefloorandallobjectscontaminatedbythismaterial,u

water.

Incaofcontactwitheyes,rinwithplentyofwaterandcontact

DoctororPoisonsInformationCentre.

Ifswallowed,IMMEDIATELYcontactDoctororPoisonsInformation

Centre.(showthiscontainerorlabel).

continued...

SPIRAXDELTA-RED

ChemwatchMaterialSafetyDataSheet(REVIEW)

IssueDate:22-Oct-2002CHEMWATCH8041-81

9317TCCD2006/2Page2of6

Section3-COMPOSITION/INFORMATIONONINGREDIENTS

NAMECASRN%

isothiazolinsas,

5-chloro-2-methyl-4-isothiazolin-3-one26172-55-4Notspec

2-methyl-4-isothiazolin-3-one2682-20-4Notspec

water7732-18-5>60

Nootheringredientinformationsupplied.

Section4-FIRSTAIDMEASURES

SWALLOWED

•

IfswalloweddoNOTinducevomiting.

•

Ifvomitingoccurs,leanpatientforwardorplaceonleftside(head-downposition,ifpossible)tomaintainopenairwayandprevent

aspiration.

EYE

Ifthisproductcomesincontactwiththeeyes:

•

Immediatelyholdeyelidsapartandflushtheeyecontinuouslywithrunningwater.

•

Ensurecompleteirrigationoftheeyebykeepingeyelidsapartandawayfromeyeandmovingtheeyelidsbyoccasionallyliftingtheupper

andlowerlids.

SKIN

Ifskinorhaircontactoccurs:

•

Immediatelyflushbodyandclotheswithlargeamountsofwater,usingsafetyshowerifavailable.

•

Quicklyremoveallcontaminatedclothing,includingfootwear.

INHALED

•

Iffumesorcombustionproductsareinhaledremovefromcontaminatedarea.

•

rmandrested.

NOTESTOPHYSICIAN

Treatsymptomatically.

Section5-FIREFIGHTINGMEASURES

EXTINGUISHINGMEDIA

Watersprayorfog.

FIREFIGHTING

AlertFireBrigadeandtellthemlocationandnatureofhazard.

Clearareaofpersonnelandmoveupwind.

•

Wearfullbodyprotectiveclothingwithbreathingapparatus.

•

Prevent,byanymeansavailable,spillagefromenteringdrainsorwatercours.

Coolfireexpodcontainerswithwatersprayfromaprotectedlocation.

Ifsafetodoso,removecontainersfrompathoffire.

Equipmentshouldbethoroughlydecontaminatedafteru.

FIRE/EXPLOSIONHAZARD

•

Thematerialisnotreadilycombustibleundernormalconditions.

•

However,itwillbreakdownunderfireconditionsandtheorganiccomponentmayburn.

Decompositionmayproducetoxicfumesofhydrogenchlorideandminoramountsofsulfuroxides(SOx).

FIREINCOMPATIBILITY

Avoidreactionwithoxidisingagents.

HAZCHEM:None

PersonalProtectiveEquipment

Gastightchemicalresistantsuit.

Limitexposuredurationto1BAt30mins.

continued...

SPIRAXDELTA-RED

ChemwatchMaterialSafetyDataSheet(REVIEW)

IssueDate:22-Oct-2002CHEMWATCH8041-81

9317TCCD2006/2Page3of6

Section6-ACCIDENTALRELEASEMEASURES

EMERGENCYPROCEDURES

MINORSPILLS

Smallquantitiesmaybedischargedtowerwithalargeexcessofwater.

perviousglovesandsafetyglass.

Wipeupnsuitablecontainersfordisposal.

Suitablecontainersarethospecifiedinstoragection.

MAJORSPILLS

ouchthespillmaterial.

Wearfullbodyprotectiveclothing

Isolateleakingcontainersandstopleakifsafetodoso.

Absorborcoverspillwithsand,earth,inertmaterialorvermiculite.

Collectresiduesandplaceinlabelledpolyethylenebag.

Floodwithan5%solutionofsodiumhypochloriteplus5%sodium

20minutescontacttime.(Minimumrecommended

ratioofdecontaminanttoproductis4:1).

Flushtowerwithcopiousquantitiesofwater.

PersonalProtectiveEquipmentadviceiscontainedinSection8oftheMSDS.

Section7-HANDLINGANDSTORAGE

PROCEDUREFORHANDLING

DONOTallowclothingwetwithmaterialtostayincontactwithskin.

doccupationalworkpractice.

Wearpersonalprotectiveequipmentwhenhandling.

Whenhandling,DONOTeat,drinkorsmoke.

Uinawell-ventilatedarea.

Keepcontainerscurelyaledwhennotinu.

Washhandswithsoapandwaterafterhandling.

Workclothesshouldbelaunderedparately:NOTathome.

SUITABLECONTAINER

•

Polyethyleneorpolypropylenecontainer.

•

Packingasrecommendedbymanufacturer.

STORAGEINCOMPATIBILITY

Avoidstoragewithoxidirsandalkalies.

STORAGEREQUIREMENTS

Obrvemanufacturer'sstoringandhandlingrecommendations.

Storeinacool,dryandwell-ventilatedarea.

Storeattemperaturebelow40degC.

•

ol.

DONOTuunlinedsteelcontainers.

egularlyforspillsandleaks.

Section8-EXPOSURECONTROLS/PERSONALPROTECTION

EXPOSURECONTROLS

ThefollowingmaterialshadnoOELsonourrecordunderthefollowingCASorChemwatch(CW)numbers

•SpiraxDelta-Red:NodataavailableforCW:8041-81

•5-chloro-2-methyl-4-isothiazolin-3-one:NodataavailableforCAS:26172-55-4

•2-methyl-4-isothiazolin-3-one:NodataavailableforCAS:2682-20-4

•water:NodataavailableforCAS:7732-18-5

PERSONALPROTECTION

continued...

SPIRAXDELTA-RED

ChemwatchMaterialSafetyDataSheet(REVIEW)

IssueDate:22-Oct-2002CHEMWATCH8041-81

9317TCCD2006/2Page4of6

Section8-EXPOSURECONTROLS/PERSONALPROTECTION

EYE

•

Safetyglasswithsideshields;orasrequired,

•

Chemicalgoggles.

HANDS/FEET

.

OTHER

OverallsandRubberapron.

•

Ensurethatthereisreadyaccesstoeyewashunit.

Ensurethereisreadyaccesstoanemergencyshower.

Thelocalconcentrationofmaterial,quantityandconditionsofudeterminethetyeofpersonalprotectiveequipmentrequired.

Forfurtherinformationconsultsitespecific

CHEMWATCHdata(ifavailable),oryour

OccupationalHealthandSafetyAdvisor.

ENGINEERINGCONTROLS

Uinawell-ventilatedarea.

Section9-PHYSICALANDCHEMICALPROPERTIES

APPEARANCE

Palegreenliquidwithamildaromaticodour;mixeswithwater.

PHYSICALPROPERTIES

Liquid.

Mixeswithwater.

MolecularWeight:NotapplicableBoilingRange(°C):100.00

MeltingRange(°C):NotavailableSpecificGravity(water=1):1.02-1.04

Solubilityinwater(g/L):MisciblepH(assupplied):Notavailable

pH(1%solution):NotavailableVapourPressure(kPa):Aswater

VolatileComponent(%vol):watercontentEvaporationRate:Aswater

RelativeVapourDensity(air=1):AswaterFlashPoint(°C):Notapplicable

LowerExplosiveLimit(%):NotapplicableUpperExplosiveLimit(%):Notapplicable

AutoignitionTemp(°C):NotapplicableDecompositionTemp(°C):Notavailable

State:Liquid

Section10-CHEMICALSTABILITYANDREACTIVITYINFORMATION

CONDITIONSCONTRIBUTINGTOINSTABILITY

Productisconsideredstableandhazardouspolymerisationwillnotoccur.

Section11-TOXICOLOGICALINFORMATION

POTENTIALHEALTHEFFECTS

ACUTEHEALTHEFFECTSCHRONICHEALTHEFFECTS

leskinnsitir*.

Mayproducediscomfortoftheeyes*.*(limitedevidence).

*(limitedevidence).

continued...

SPIRAXDELTA-RED

ChemwatchMaterialSafetyDataSheet(REVIEW)

IssueDate:22-Oct-2002CHEMWATCH8041-81

9317TCCD2006/2Page5of6

Section11-TOXICOLOGICALINFORMATION

TOXICITYANDIRRITATION

oindividualconstituents.

unlessotherwispecifieddataextractedfromRTECS-RegisterofToxicEffectsofChemicalSubstances

5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:

Nosignificantacutetoxicologicaldataidentifiedinliteraturearch.

Bacterialmutagen

ConsideredtobethemajornsitirinKathonCG(1)

(1).Bruzeetal-ContactDermatitis20:219-39,1989

2-METHYL-4-ISOTHIAZOLIN-3-ONE:

Noneavailable.

Bacterialmutagen

ConsideredtobeaminornsitirinKathonCG(1)

(1).Bruzeetal-ContactDermatitis20:219-39,1989

WATER:

Nosignificantacutetoxicologicaldataidentifiedinliteraturearch.

Section12-ECOLOGICALINFORMATION

NodataforSpiraxDelta-Red.

Refertodataforingredients,whichfollows:

5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:

Octanol/waterCoefficient=0.401(logP)

Biodegradation(aquaticmetabolism)

halflifet1/2anerobic=4.8hours

halflifet1/2aerobic=17.3hours

asmixedisothiazolinones

RainbowtroutLC50(96hr)=0.19mg/L.

BluegillSunfishLC50(96hr)=0.28mg/L.

DaphniaEC50(48hr)=0.16mg/L.

AlgalSelenastrumEC50:0.018mg/L.

2-METHYL-4-ISOTHIAZOLIN-3-ONE:

Octanol/watercoefficient=-0.486(logP)

Biodegradation(aquaticmetabolism)

halflifet1/2(aerobic)=9.1hours

asmixedisothiazolinones

RainbowtroutLC50(96hr):=0.19mg/L.

BluegillsunfishLC50(96hr):=0.28ml/L.

DaphniaEC50(48hr):=0.16mg/L.

Algal(Selenastrum)EC50:0.018mg/L.

Section13-DISPOSALCONSIDERATIONS

tmanufacturerforrecyclingoptions.

ConsultStateLandWasteManagementAuthorityfordisposal.

Buryorincinerateresidueatanapprovedsite.

DONOTdischargeintowerorwaterways.

Recyclecontainersifpossible,ordispoofinanauthoridlandfill.

Section14-TRANSPORTATIONINFORMATION

HAZCHEM:None

NOTREGULATEDFORTRANSPORTOFDANGEROUSGOODS:UN

continued...

SPIRAXDELTA-RED

ChemwatchMaterialSafetyDataSheet(REVIEW)

IssueDate:22-Oct-2002CHEMWATCH8041-81

9317TCCD2006/2Page6of6

Section15-REGULATORYINFORMATION

POISONSSCHEDULE:None

REGULATIONS

5-chloro-2-methyl-4-isothiazolin-3-one(CAS:26172-55-4)isfoundonthefollowingregulatorylists;

AustraliaInventoryofChemicalSubstances(AICS)

OECDReprentativeListofHighProductionVolume(HPV)Chemicals

2-methyl-4-isothiazolin-3-one(CAS:2682-20-4)isfoundonthefollowingregulatorylists;

AustraliaInventoryofChemicalSubstances(AICS)

water(CAS:7732-18-5)isfoundonthefollowingregulatorylists;

AustraliaInventoryofChemicalSubstances(AICS)

OECDReprentativeListofHighProductionVolume(HPV)Chemicals

Section16-OTHERINFORMATION

DenmarkAdvisorylistforlfclassificationofdangeroussubstances

SubstanceCASSuggestedcodes

5-chloro-2-methyl-4-isothiazolin-26172-55-R43

3-one4

2-methyl-4-isothiazolin-3-one2682-20-R43

4

romanyfairdealingforthepurposof

privatestudy,rearch,revieworcriticism,aspermittedundertheCopyright

Act,nopartmaybereproducedbyanyprocesswithoutwrittenpermissionfrom

(+613)95724700.

IssueDate:22-Oct-2002

PrintDate:24-Jul-2006