dcm化学

ABO2,7,8-Trioxabicyclo[3.2.1]octyl

AcAcetyl

ACBZ4-Azidobenzyloxycarbonyl

ACEα-Chloroethoxycarbonyl

AcHmb2-Acetoxy-4-methoxybenzyl

AcmAcetamidomethyl

Ad1-Adamantyl

Adoc1-Adamantyloxycarbonyl

Adpoc1-(1-Adamantyl)-1-methylethoxycarbonyl

AIBN2,2’-Azobis(2-methylpropionitrile)or

Azobisisobutyronitrile

AllAllyl

AllocAlloxycarbonyl

AlsAllylsulfonyl

AMB2-(Acetoxymethyl)benzoyl

AN4-Methoxyphenyloranisyl

Anpe2-(4-Acetyl-2-nitrophenyl)ethyl

AOAtomicorbital

AOCAllyloxycarbonyl

p-AOMp-Anisyloxymrthylor(4-methoxyphenoxy)methyl

ArAryl

atmAtmosphere

ATPAdenosine5’-triphosphate

ATPaAdenosinetriphosphata

Azbp-Azidobenzyl

BamBenzamidomethyl

BBAButane-2,3-bisacetal

BBnp-Bromobenzyl

9-BBN9-Borabicyclo[3.3.1]nonane

BDMSBiphenyldimethylsilyl

BDT1,3-Benzodithiolan-2-yl

Bic5-Benzisoxazolymethoxycarbonyl

Bmpc2,4-Dimethylthiophenoxycarbonyl

Bmpm1,1-Bis(4-methoxyphenyl)-1’-pyrenylmethyl

BMSBorane-methylsulfide

BnBenzyl

BOCt-Butylcarbonyl

t-BOCt-Butylcarbonyl

BOMBenzyloxymethyl

BOPBenzotriazol-1-yloxytris(dimethylamino)

phosphoniumhexafluorophosphate

BOP-ClN,N-Bis(2-oxo-3-oxazolidinyl)phosphinic

bpBoilingpoint

Bpoc1-methyl-1-(4-biphenyl)ethoxycarbonyl

Bpy2,2’-Bipyridyl

brBroad(spectral)

BSABistrimethylsilylacetamide

BtBenzotriazo-1-ylor1-benzotriazolyl

BTBABenzyltributylammoniumchloride

BuButyl

s-BUSec-Butyl

t-Butert-Butyl

Bumt-Butoxymethyl

t-Bumeoc

1-(3,5-Di-t-butylphenyl)-1-methylethoxycarbonyl

BzBenzoxyl

oCDegreeCelsius

calcdCalculated

CamCarboxyamidomethyl

cAMPAdenosinecyclic3’,5’-phosphate

CANCerium(IV)ammoniumnitrate

CbzBenzyloxycarbonyl

CDCirculardichrosim

CDI1,1’-Carbonyldiimidazole

Cee1-(2-Chloroethoxy)ethyl

CIChemicalionization(inMS)Configurationinteraction

(inMOtheory)

CIDNPChemicallyinduceddynamicnuclearpolarization

cmCentmeter

CMPI2-Chloro-1-methylpyridiumchloride

CNDOCompleteneglectofdifferentialoverlap

CocCinnamyloxycarbonyl

COD1,5-Cyclooctadiene

concdConcentrated

COSYCorrelationspectroscopy

COTCyclooctatetrene

CpCyclopentadienyl

CPTr4,4’,4”-Tris(4,5-dichlorophthalimido)riphenylmethyl

CSACamphorsulfonicacid

CTMP

1-[(2-Chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl

CysCysteine

δChemicalshiftinppm

dDay,doublet(spectral)

DABCO1,4-Diazabicyclo[2.2.2]octane

DAMDi(4-methoxyphenyl)methyl

DASTDiethylaminosulfurtrifluoride

DB-t-BOC1,1-Dmethyl-2,2-dibromoethoxycarbonyl

DBD-Tmoc

2,7-Di-t-butyl[9-(10,10-dioxo-10,10,10,10-tetrahydrothiox

anthyl)methylcarbonyl

DBN1,5-Diazabicyclo[4.3.0]non-5ene

DBU1,8-Diazabicyclo[5.4.0]undec-7-ene

DCCDicyclohexylcarbodiimide

DCMMEDichloromethylammoniumchloride

DDQ2,3-Dichloro-5,6-dicyano-1,4-benzoquinone

deDiastereomericexcess

DEADDiethylazodicarboxylate

DEIPSDiethylisopropylsilyl

DEPTDistortionlesnhancementbypolarizationtransfer

DGDiacylglycerol

DIADDiisopropylazodicarboxylate

DIBAHDiisobutylalumiumhydride

DIBALDiisobutylaluminumhydride

Dim2-(1,3-Dithianyl)methyl

DIPEADiisopropylethylamine

DIPTDiisopropyltartrate

DMACDimethylacetamide

DMADDiethylacetylenedicarboxylate

DMAP4-Dimethylaminopyridine

DMEDimethoxyethane

DMFN,N-Dimethylformamide

DMIPSDimethylisopropylsilyl

DmocDithianylmethoxycarbonyl

DMPDimethylpropane

DmpDimethylphosphinyl

DMPM3,4-Dimethoxybenzyl

DMPU

1,3-Dimethyl-3,4,5,6-tetrhydro-2(1H)-pyrimidinone

DMSDimethylsulfate

DMSODimethylsulfoxideormethylsulfoxide

DMTDimethoxytrityl

DMTrDi(p-methoxyphenyl)phenylmethyl

DNADeoxyribonucleicacid

DNBp,p’-Dinitrobenzhyrryl

DNMBS

4-(4’,8’-Dimethoxynaphthylmethyl)benzenesulfonyl

DNP2,4-Dinitrophenyl

Dobzp-(Dihydroxyboryl)benzyloxycarbonyl

DPMDiphenylmethyl

DPMSDiphenylmethylsilyl

DppDiphenylphosphinyl

DPPADiphenylphosphorylazide

Dppe2-(Diphenylphosphino)ethyl

Dppm(Diphenyl-4-pyridyl)methyl

DptDiphenylthiophosphinyl

DTBMSDi-t-butylsilylene

DtsDithiasuccinimidyl

E1Unimolecularelimination

E2Bimolecularelimination

ED50Dothatiffectivein50%oftestsubjects

EDC1-Ethyl-3-(3’-dimethylaminopropyl)carbodiimide

EDTAEthylenediaminetetraaceticacid

EE1-Ethoxyethyl

eeEnantiomericexcess

EIElectronimpact(inMS)

ESRElectronspinresonance

EtEthyl

FABFastatombombardment(inMS)

Fcm-NR2N-Ferrocenylmethyl

FDFielddistortion(inMS)

FGFounctionalgroup

FIDFlameionizationdetectionorFreeinduceddecay(in

NMR)

Fm9-Fluorenylmethyl

FMOC9-Fluorenylmethylcarbamate

Fpη5

FTFoutiertransform

gGram

GCGaschromatography

GTPGuanosine5’-triphosphate

GUMGuaiacolmethyl

hHour

HCAHexachloroacetone

HexHexyl

HMDS1,11,3,3,3-Hexamethyldisilazane

HMOHuckelmolecularorbital

HMPAHexamethylphosphoramide

HMPTHexamethylphosphoroustriamide

HOBT1-Hydroxybenzotriazole

HOMOHighestoccupiedmolecularorbital

HPLCHighperformanceliquidchromatography

HRMSHigh-resolutionmassspectrum

hνIrradiationwithlight

HzHertz

hZHomobenzyloxycarbonyl

ICRIoncyclotronresonance

IDTr

3-(Imidazole-1-ylmethyl)-4’,4”-dimethoxytriphenylmethyl

ImImidazole-1-ylor1-imidazolyl

iMds2,6—Dimethoxy-4-methylbenzenesulfonyl

INDOIncompleteneglectofdifferentialoverlap

IPIonizationpotential

Ipaoc1-Isopropylallyloxycarbonyl

IPDMSIsopropyldimethylsilyl

IRInfrared

JCouplingconstant(inNMR)

kKilo

KAPAPotassium3-aminopropylamide

KHMDSPotassiumbis(trimethylsilyl)amideorpotassium

hexamrthyldisilane

LTriphenylphosphineligandorliter

LAHLithiumaluminumhydride

LCAOLinearcombinationofatomicorbitals

LDALithiumdiisopropylamide

LDBB4,4’-Di-tert-butyybiphenylylide

LevLevulinoyl

LevSLevulinoyldithioacetalester

4,4-(ethylenedithio)pentanoyl

LFERLinearfreeenergyrelationship

LICALithiumisopropylcyclohexylamide

LHMDSLithiumbis(trimethylsilyl)amideorlithium

hexamrthyldisilane

LTALeadtetraacetate

LTMPLithium2,2,6,6-tetramethylpiperidide

LUMOLowestunoccupiedmolecularorbital

μMicro

mMultiple(spectral),meter,milli

MMolesperliterormega

MADMethylaluminum

bis(2,6-di-t-butyl-4-methylphenoxide

MBE1-(Methyl-1-benzyloxyethyl

MBF

2,3,3a,4,5,6,7,7a-Octahydro-7,8,8-trimethyl-4,7-methanob

enzofuran2-yl

MBSp-Methoxybenzenesulfonyl

MCPBAm-Chloroperbenzoicacid

Mds2,6-Dimethyl-4-methoxybenzenesulfonyl

m/eMasstochargeratio(inMS)

MEMα-Methoxyethoxymethyl

MeOZp-Methoxybenzyloxycarbonyl

MesMesityl2,4,6-trimethylphenyl

MHzMegahertz

minMinute

MINDOModifiedintermediateneglectofdifferential

overlap

mMMillimolesperliter

MMTrp-Methoxyphenyldiphenylmethyl

MOMolecularorbital

molMole

MOMMethoxymethyl

MoOPHOxodiperoxymolybdenum(pyridine)

hexamethylphosphoramide

Mozp-Methoxybenzyloxycarbonyl

mpMeltingpoint

MPMp-Methoxyphenylmethylorp-Methoxybenzyl

Mpsp-Methoxyphenylsufonyl

MptDimethylthiophosphinyl

mRNAMesngerRNA

MsMethanesulfonylormesyl

MSMassspectrometry

MSAMethanesulfonicacid

Msib4-(Methylsulfinyl)benzyl

Msz4-Methylsulfinylbenzyloxycarbonyl

Mtb2,4,6-Trimethoxybenzenesufonyl

Mte2,3,5,6-Tetramethyl-4-methoxybenzenesulfonyl

MTHP4-Methoxytetrahydropyranyl

MTMMethylthiomethyl

MTMB4-(methylthiomethoxy)butyryl

MTMECO2-(Methylthiomethoxy)ethoxycarbonyl

MTMT2-(Methylthiomethoxymethyl)benzoxy

Mtpc4-Methylthiophenoxycarbonyl

Mtr2,3,6-Trimethyl-4-methoxybenzenesulfonyl

Mts2,3,6-Trimethylbenzenesulfonyl(mesitylenesulfonyl)

m/zMasstochargeratio(inMS)

nnao

NADNicotinamideadeninedinucleotide

NADHReducedNAD

NBAN-Bromoacetamide

NBSN-Bromosuccinimide

NCSN-Chlorosuccinimide

Ni(acac)2Nickelacetylacetonate

NISN-Iodosuccinimide

Ni(R)RaneyNickel

NMMN-Methylmorpholine

NMRNuclearmagneticresonance

Noc4-Nitrocinnamyloxycarbonyl

NOENuclearOverhaureffect

NOESYNuclearOverhaureffectspectroscopy

NPS2-Nitrophenylsulfenyl

Npys3-Nitro-2-pyridinesulfenyl

NuNucleophile

ODOpticaldensity

ONBo-Nitrobenzyl

ORDOpticalrotarydispersion

otOventemperature

PADAPotassiumazodicarboxylate

PCCPyridiniumchlorochromate

PDCPyridiniumdichromate

PdCl2(tpp)2

Dichlorobis[tris(2-methylphenyl)phosphine]palladium

Pd2(dba)3Tris(dibenzylideneacetone)dipalladium

PEPhotoelectron

Peoc2-Phosphonioethoxycarbonylor

2-(Triphenylphosphonio)ethoxycarbonyl

Pet2-(2’-Pyridyl)ethyl

PGProtectivegroup

PhPhenyl

φPhenyl

Phen1,10-Phenanthroline

Phenoc4-Methoxyphenacyloxycarbonyl

PhthPhthaloyl

Pixyl9-(9-Phenyl)xanthenyl

PMBp-Methoxybenzyl

PMBMp-Methoxybenzoxymethyl

Pmc2,2,5,7,8-Pentamethylchroman-6-sulfonyl

PmePentamethylbenzenesulfonyl

PMSp-Methylbenzylsulfonyl

PNBp-Nitrobenzoyl

PNBSPp-Nitrobenzenesulfonylperoxide

POM4-PentenyloxymethylorPivaloxymethyl

PPAPolyphosphoricacid

PPEPolyphosphateester

ppmPartspermollion

Ppoc2-Triphenylphosphonioisopropoxycarbonyl

PPTSPyridiniump-to;uenesulfonate

PrPropyl

i-PrIsopropyl

Pc2-(Phenylsulfonyl)ethoxycarbonyl

PTMPhenylthiomethyl

PTCPha-transfercatalysis

PvPivaloyl

PyPyridine

Pyoc2-(2’-and4’-pyridyl)ethoxycarbonyl

qQuartet

RfRetentionfactor

rRNARibosomalRNA

rtRoomtemperature

sSingletorcond

ScmS-Carboxymethylsulfenyl

ScmClMethoxycarbonylsulfenylchloride

SEMTrimethylsilylmeyhoxyethyl

SESβ-Trimethylsilylethanesulfonyl

SETSingleelectrontransfer

SMOM(Phenyldimethylsilyl)methoxymethyl

SN1Unimolecularnucleophilicsubstitution

SN2Bimolecularnucleophilicsubstitution

SN’Nucleophilicsubstitutionwithallylicrearrangement

SnmS-(N’-Methyl-N’-phenylcarbamoyl)sulfenyl

STABASE1,1,4,4-Tetramethyldisilylazacyclopentane

SuSuccinimidyl

tTriplet

TacmTrimethylacetamidomethyl

TBAFTetrabutylammoniumfluoride

TBAITetrabutylammoniumiodide

TBDMSt-Butyldimethylsilyl

TBDPSt-Butyldiphenylsilyl

TBDSTetra-t-butoxydisiloxane-1,3-diylidene

TBHPt-Butylhydroperoxide

TBMPSt-Butylmethoxyphenylsilyl

TBSTributylsilane

TBTr4,4’-4”-Tris(benzyloxy)triphenylmethyl

TcBoc1,1-Dimethyl-2,2,2-trichloroethoxycarbonyl

TCNETetracyanoethylene

TCNQ7,7,8,8-Tetracyanoquinodimethane

Tcroc2-(Trifluoromethyl)-6-chromonylmethylene

carbonyl

Tcrom2-(Trifluoromethyl)-6-chromonylmethylene

TDSThexyldimethylsilyl

TEATriethylamine

TEABTetraethylammoniumbromide

TEBACBenzyltriethylammoniumchloride

Tebbs’

TEDTriethylenediamine

Teoc2-(Trimethylsilyl)ethoxycarbonyl

TESTriethylsilyl

TfTrifluoromethanesulfonyl

TFATrifluoroaceticacid

TFAATrifluoroaceticacid

TfOHTrifluoromethanesulfonicacid

Thexyl2,3-Dimethyl-2-butyl

THFTetrahydrofuran

THPTetrahydropyran

TIPDS1,3-(1,13,3-Tetraisopropyldisiloxanyllidene)

TIPSTriisopropylsilyl

TLTr4,4’,4”-Tris(levulinoxy)triphenylmethyl

TMEDAN,N,N’,N’-Tetramethylethylenediamine

TMG1,1,3,3-Tetramethylguanidine

TMP2,26,6-Tetramethylpiperidine

TMPMTrimethoxyphenylmethyl

TMSTrimethylsilylorTetramethylsilane

TMSEC2-(Trimethylsilyl)ethoxycarbonyl

TMTrTri(p-methoxyphenyl)methyl

TolTolyl

Torr1mmHg

Tosp-Toluenesulfonyl

TPAPTetrapropylammoniumperruthanate(Pr)4NRuO4

TPPTetraphenylporphine

TPSTriisopropylbenzenesulfonyl

TPSTriphenylsilyl

tRRetentiontime

TrTrityl(triphenylmethyl)

TritonBBenzyltrimethylammoniumhydroxide

Tritylone9-(9-Phenyl-10-oxo)anthryl

Troc2,2,2-Trichloroethoxycarbonyl

Tsp-ToluenesulfonylorTosyl

TSTransitionstate

TSAp-Toluenesulfonicacid

T2-(p-Toluenesulfonyl)ethyl

TsOHp-Toluenesulfonicacid

TyrOHTyrosine

UVUltraviolet

VocVinyloxycarbonyl

ZBenzyloxycarbonyl